Crystal growth, thermal and optical studies on a metalorganic nonlinear optical material dipotassium boro maleate (DKBM)

被引：11

作者：

Bharthasarathi, T. ^{[1
]}

Arulmozhichelvan, P. ^{[1
]}

Murugakoothan, P. ^{[1
]}

机构：

[1] Pachaiyappas Coll, PG & Res Dept Phys, Madras 600030, Tamil Nadu, India

来源：

MATERIALS LETTERS | 2010年 / 64卷 / 13期

关键词：

Metalorganic; Solution growth; Slow evaporation; X-ray diffraction; Nonlinear crystal; GENERATION; ION;

D O I：

10.1016/j.matlet.2010.04.005

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A single crystal of dipotassium boro maleate (DKBM) was grown using slow evaporation method The solubility of DKBM was determined for various temperatures The structure of the grown crystal was confirmed by single crystal X-ray diffraction (SXRD) and powder X-ray diffraction (PXRD) techniques The Fourier transform infrared (FT-IR) study reveals the various functional groups present in the grown crystal The UV-Vis-NIR spectra revealed the transmission properties of the grown crystal Thermal stability of the crystal was investigated using therm gravimetric analysis (TGA) and differential thermal analysis (DTA) The nonlinear optical (NLO) property of the crystal was confirmed by powder second harmonic generation (SHG) test (C) 2010 Elsevier B V All rights reserved

引用

页码：1506 / 1509

页数：4

共 14 条

[1] VIBRATIONAL ANALYSIS OF THE HYDROGEN MALEATE ION USING SCALED ABINITIO FORCE-CONSTANTS [J].

AVBELJ, F ;

HODOSCEK, M ;

HADZI, D .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1985, 41 (1-2) :89-97

[2] VIBRATIONAL-SPECTRA OF POTASSIUM HYDROGEN MALEATE CRYSTAL AND SOLUTION [J].

AVBELJ, F ;

OREL, B ;

KLANJSEK, M ;

HADZI, D .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1985, 41 (1-2) :75-87

[3] Efficient generation of coherent blue and green light based on frequency conversion in KTiOPO4 crystals [J].

Ding, YJ ;

Mu, XD ;

Gu, XH .

JOURNAL OF NONLINEAR OPTICAL PHYSICS & MATERIALS, 2000, 9 (01) :21-53

[4]

Holden A., 1960, CRYSTALS CRYSTAL GRO

[5]

HOU WB, 1993, J CRYST GROWTH, V71, P133

[6] 2ND-HARMONIC GENERATION IN ZINC TRIS(THIOUREA) SULFATE [J].

MARCY, HO ;

WARREN, LF ;

WEBB, MS ;

EBBERS, CA ;

VELSKO, SP ;

KENNEDY, GC ;

CATELLA, GC .

APPLIED OPTICS, 1992, 31 (24) :5051-5060

[7]

MUSTAFA T, 2007, ACTA CRYSTALLOGR C, V63, pM430

[8] NORMAL COORDINATE ANALYSES OF HYDROGEN-BONDED COMPOUNDS .3. ACID MALEATE ION [J].

NAKAMOTO, K ;

SARMA, YA ;

BEHNKE, GT .

JOURNAL OF CHEMICAL PHYSICS, 1965, 42 (05) :1662-&

[9]

Nakamoto K., 1968, INFRARED RAMAN SPECT

[10] Growth and characterization of a new metal-organic crystal: potassium thiourea bromide [J].

Roshan, A ;

Joseph, C ;

Ittyachen, MA .

MATERIALS LETTERS, 2001, 49 (05) :299-302

← 1 2 →