Palladium-catalyzed hydroesterification of olefins with isosorbide in standard and Bronsted acidic ionic liquids

被引：8
|
作者：
Boulanger, Jerome [1 ]
Seingeot, Adeline [1 ]
Leger, Bastien [1 ]
Pruvost, Romain [2 ]
Ibert, Mathias [3 ]
Mortreux, Andre [2 ]
Chenal, Thomas [2 ]
Sauthier, Mathieu [2 ]
Ponchel, Anne [1 ]
Monflier, Eric [1 ]
机构：
[1] Univ Artois, Fac Sci Jean Perrin, UCCS, UMR 8181, F-62307 Lens, France
[2] Univ Lille, UCCS, UMR 8181, ENSCL, F-59650 Villeneuve Dascq, France
[3] Roquette Freres, F-62136 Lestrem, France
来源：
CATALYSIS COMMUNICATIONS | 2015年 / 69卷
关键词：
Hydroesterification; Isosorbide; Palladium; Ionic liquids; Biphasic catalysis; STYRENE DERIVATIVES; HYDROALKOXYCARBONYLATION; PROMOTER; MEDIA;
D O I：
10.1016/j.catcom.2015.06.008
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The palladium catalyzed hydroesterification of 1-octene with isosorbide was studied in standard and Bronsted acidic ionic liquids as reaction media. High conversions and selectivities towards the targeted isosorbide diesters have been achieved by using a catalytic system composed of Pd(OAc)(2) and trisulfonated triphenylphosphine dissolved in 1-(4-sulfonic acid)-butyl-3-methylimidazolium tosylate. The catalytic phase can be reused several times without any significant decrease in activity and selectivity. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：143 / 146
页数：4
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