Palladium-catalyzed hydroesterification of olefins with isosorbide in standard and Bronsted acidic ionic liquids

被引：8

作者：

Boulanger, Jerome ^{[1
]}

Seingeot, Adeline ^{[1
]}

Leger, Bastien ^{[1
]}

Pruvost, Romain ^{[2
]}

Ibert, Mathias ^{[3
]}

Mortreux, Andre ^{[2
]}

Chenal, Thomas ^{[2
]}

Sauthier, Mathieu ^{[2
]}

Ponchel, Anne ^{[1
]}

Monflier, Eric ^{[1
]}

机构：

[1] Univ Artois, Fac Sci Jean Perrin, UCCS, UMR 8181, F-62307 Lens, France

[2] Univ Lille, UCCS, UMR 8181, ENSCL, F-59650 Villeneuve Dascq, France

[3] Roquette Freres, F-62136 Lestrem, France

来源：

CATALYSIS COMMUNICATIONS | 2015年 / 69卷

关键词：

Hydroesterification; Isosorbide; Palladium; Ionic liquids; Biphasic catalysis; STYRENE DERIVATIVES; HYDROALKOXYCARBONYLATION; PROMOTER; MEDIA;

D O I：

10.1016/j.catcom.2015.06.008

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The palladium catalyzed hydroesterification of 1-octene with isosorbide was studied in standard and Bronsted acidic ionic liquids as reaction media. High conversions and selectivities towards the targeted isosorbide diesters have been achieved by using a catalytic system composed of Pd(OAc)(2) and trisulfonated triphenylphosphine dissolved in 1-(4-sulfonic acid)-butyl-3-methylimidazolium tosylate. The catalytic phase can be reused several times without any significant decrease in activity and selectivity. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：143 / 146

页数：4

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