Acoustic determination of thermodynamic properties of ternary liquid mixtures up to 150 MPa

被引:27
作者
Daridon, JL [1 ]
Lagourette, B [1 ]
Lagrabette, A [1 ]
机构
[1] Univ Pau & Pays Adour, CNRS, Lab Haute Press, F-64000 Pau, France
关键词
ternary mixtures; ultrasonic velocities;
D O I
10.1080/00319109908045122
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ultrasonic velocity measurements were carried out on two ternary mixtures at pressures up to 150 MPa and within a temperature interval of 293 K- 373 K. The first of these two mixtures, which was selected to simulate a distillation cut close to 423 K, is made up tin mass percentage) of 40% nonane, 35% cyclooctane and 25% propylbenzene; the second, made up of 40% undecane, 35% pentylcyclohexane and 25% pentylbenzene has a boiling point of approximately 473 K. The acoustic measurements were then used to characterize the p rho T behaviour of these two ternary mixtures in the liquid state. They also provided indirect access to the isentropic and isothermal compressibility coefficients of these mixtures.
引用
收藏
页码:137 / 160
页数:24
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