Dehydration of fructose into 5-hydroxymethylfurfural in acidic ionic liquids

被引：55

作者：

Tao, Furong ^{[1
,2
]}

Song, Huanling ^{[1
]}

Chou, Lingjun ^{[1
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

来源：

RSC ADVANCES | 2011年 / 1卷 / 04期

关键词：

HETEROGENEOUS ZIRCONIUM; SUBCRITICAL WATER; CATALYSTS; CONVERSION; GLUCOSE; 5-HYDROXYMETHYL-2-FURALDEHYDE; SUBSTANCES; SYSTEM; SUGARS;

D O I：

10.1039/c1ra00088h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple and effective process for the dehydration of fructose into 5-hydroxymethylfurfural (HMF) using ionic liquid 1-(4-sulfonic acid) butyl-3-methylimidazolium hydrogen sulfate (IL-1) as the catalyst was developed. High fructose conversion of 100% with HMF yield of 94.6% was obtained at 120 degrees C for 180 min reaction time in water-4-methyl-2-pentanone (MIBK) biphase system. Generally, the increase of water content had a negative effect on the reaction, the HMF selectivity decreased as the excessive elevation of temperature and prolonging of time, which suggested the decomposition of HMF. The ionic liquid IL-1 could be recycled and exhibited constant activity for six successful runs. This paper provided a new strategy for HMF production from fructose.

引用

页码：672 / 676

页数：5

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