Germanium nanowire synthesis: An example of solid-phase seeded growth with nickel nanocrystals

被引：88

作者：

Tuan, HY ^{[1
]}

Lee, DC ^{[1
]}

Hanrath, T ^{[1
]}

Korgel, BA ^{[1
]}

机构：

[1] Univ Texas, Dept Chem Engn, Texas Mat Inst, Ctr Nano & Mol Sci Technol, Austin, TX 78712 USA

来源：

CHEMISTRY OF MATERIALS | 2005年 / 17卷 / 23期

关键词：

D O I：

10.1021/cm0513031

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Germanium nanowires were synthesized by thermal decomposition of diphenyl germane in the presence of nickel (Ni) nanocrystals in supercritical toluene at 27.8 MPa and temperatures ranging from 410 to 460 degrees C. The growth temperature is well below the lowest Ni-Ge eutectic temperature (762 degrees C), and nanowire crystallization appears to occur by solid-phase alloying of the seed particle. We call this nanowire growth mechanism supercritical fluid-solid-solid (SFSS) synthesis.

引用

页码：5705 / 5711

页数：7

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