cis-Aquadichlorido[pyrimidin-2(1H)-one-κN3]copper(II)

被引：0

作者：

Kurawa, Mukhtar A. ^{[1
]}

Adams, Christopher J. ^{[1
]}

Orpen, A. Guy ^{[1
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷

关键词：

D O I：

10.1107/S1600536808018771

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [CuCl2(C4H4N2O)(H2O)], the Cu-II cation is coordinated by two chloride anions, one pyrimidin-2-one N atom and one water molecule, giving a slightly distorted square-planar geometry. In the crystal structure, the pyrimidin-2-one rings stack along the b axis, with an interplanar distance of 3.306 angstrom, as do the copper coordination planes (interplanar spacing = 2.998 angstrom). The coordination around the Jahn-Teller-distorted CuII ion is completed by long Cu center dot center dot center dot O [3.014 (5) angstrom] and Cu center dot center dot center dot Cl [3.0194 (15) angstrom] interactions with adjacent molecules involved in this stacking. Several N H center dot center dot center dot Cl, O-H center dot center dot center dot Cl and O-H center dot center dot center dot O intermolecular hydrogen bonds form a polar three-dimensional network.

引用

页码：M969 / U1010

页数：10