Characterization of binary solvent mixtures of DMSO with water and other cosolvents

被引：184
|
作者：
Catalán, J [1 ]
Díaz, C
García-Blanco, F
机构：
[1] Univ Autonoma Madrid, Dept Quim Fis Aplicada, Madrid 28049, Spain
[2] Univ Complutense Madrid, Fac Farm, Dept Quim Fis, E-28040 Madrid, Spain
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2001年 / 66卷 / 17期
关键词：
D O I：
10.1021/jo010415i
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Binary mixtures of DMSO with nine different cosolvents were characterized in light of the pure solvent scales, using suitable probe/homomorph couples. Various physical (vapor pressure, surface tension, viscosity, and enthalpy of mixing) and spectroscopic (IR and NMR) properties of the DMSO/ water mixtures are described in terms of their polarity, acidity, and basicity, and the descriptions are examined with a view to establishing their potential physical significance.
引用
收藏
页码：5846 / 5852
页数：7
相关论文
共 50 条
  • [21] Characterization and Structure Analysis of Cefodizime Sodium Solvates Crystallized from Water and Ethanol Binary Solvent Mixtures
    Liu, Zengkun
    Yin, Qiuxiang
    Zhang, Xinwei
    Gong, Junbo
    Xie, Chuang
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2014, 53 (08) : 3373 - 3377
  • [22] ULTRASONIC STUDY OF BINARY-MIXTURES OF SOME MONOHYDROXY ALCOHOLS, KETONES, AND NITROBENZENE WITH DMSO AS COMMON SOLVENT
    DAS, AK
    JHA, BL
    JOURNAL OF MOLECULAR LIQUIDS, 1994, 59 (2-3) : 161 - 171
  • [23] Picosecond solvation dynamics-A potential viewer of DMSO-Water binary mixtures
    Banik, Debasis
    Kundu, Niloy
    Kuchlyan, Jagannath
    Roy, Arpita
    Banerjee, Chiranjib
    Ghosh, Surajit
    Sarkar, Nilmoni
    JOURNAL OF CHEMICAL PHYSICS, 2015, 142 (05):
  • [24] EMPIRICAL PARAMETERS OF LEWIS BASICITY OF BINARY SOLVENT MIXTURES .2. MIXTURES WITH WATER
    WRONA, PK
    KRYGOWSKI, TM
    ZIELKOWSKA, U
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1989, 44 (06): : 673 - 678
  • [25] VAPORIZATION OF BINARY SOLVENT MIXTURES
    KAST, W
    CHEMIE INGENIEUR TECHNIK, 1979, 51 (02) : 152 - 152
  • [26] Thermochemistry of benzene solution in water-aprotic solvent binary mixtures
    Batov, DV
    Antonova, OA
    Korolev, VP
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2001, 71 (08) : 1215 - 1219
  • [27] Thermochemistry of Benzene Solution in Water-Aprotic Solvent Binary Mixtures
    D. V. Batov
    O. A. Antonova
    V. P. Korolev
    Russian Journal of General Chemistry, 2001, 71 : 1215 - 1219
  • [28] Thermodynamic aspects of phase equilibrium in binary water–organic solvent mixtures
    L. N. Mizerovskii
    Russian Journal of Physical Chemistry A, 2017, 91 : 310 - 314
  • [29] Thermochemistry of Aniline Solution in Binary Mixtures Water-Aprotic Solvent
    D. V. Batov
    O. A. Antonova
    V. P. Korolev
    Russian Journal of General Chemistry, 2001, 71 : 689 - 695
  • [30] Thermochemistry of aniline solution in binary mixtures water-aprotic solvent
    Batov, DV
    Antonova, OA
    Korolev, VP
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2001, 71 (05) : 689 - 695
12345