Characterization of binary solvent mixtures of DMSO with water and other cosolvents

被引：184

作者：

Catalán, J ^{[1
]}

Díaz, C

García-Blanco, F

机构：

[1] Univ Autonoma Madrid, Dept Quim Fis Aplicada, Madrid 28049, Spain

[2] Univ Complutense Madrid, Fac Farm, Dept Quim Fis, E-28040 Madrid, Spain

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2001年 / 66卷 / 17期

关键词：

D O I：

10.1021/jo010415i

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Binary mixtures of DMSO with nine different cosolvents were characterized in light of the pure solvent scales, using suitable probe/homomorph couples. Various physical (vapor pressure, surface tension, viscosity, and enthalpy of mixing) and spectroscopic (IR and NMR) properties of the DMSO/ water mixtures are described in terms of their polarity, acidity, and basicity, and the descriptions are examined with a view to establishing their potential physical significance.

引用

页码：5846 / 5852

页数：7

共 53 条

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