Crystal Structure of (CN3H6)2[Eu(edta)F(H2O)] • 2H2O

被引：0

作者：

Mistryukov, V. E. ^{[1
]}

Mikhailov, Yu. N. ^{[1
]}

Chuklanova, E. B. ^{[1
]}

Sergeev, A. V. ^{[1
]}

Shchelokov, R. N. ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 1998年 / 43卷 / 12期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Guanidinium aquafluoro(ethylenediaminetetraacetato)europeate (CN(3)H(6))(2)[Eu(edta)F(H(2)O)] center dot 2H(2)O was prepared and structurally studied by X-ray diffraction (Syntex P2(1) automated diffractometer, lambda MoK(alpha), 4722 unique nonzero reflections with I > sigma(I), omega/theta scanning, theta(max) = 30 degrees). The crystals are monoclinic with a = 11.436(5) angstrom, b = 19.469(2) angstrom, c = 11.758(4) angstrom, beta = 117.81(3)degrees, space group P2(1)/n, Z= 4. The structure was solved by the heavy-atom method and refined in anisotropic approximation with fixed hydrogen atoms to R = 0.028; hydrogen atoms were located from a difference synthesis; positional atomic parameters are given in the table. All calculations were performed with the SHELX86 program package.

引用

页码：1862 / 1864

页数：3