Selective Conversion of CO2 and Switchable Alcohols into Linear or Cyclic Carbonates via Versatile Zinc Catalysis

被引：15

作者：

Song, Qing-Wen ^{[1
]}

Zhao, Qing-Ning ^{[1
]}

Li, Jing-Yuan ^{[1
]}

Zhang, Kan ^{[1
]}

Liu, Ping ^{[1
]}

机构：

[1] Chinese Acad Sci, State Key Lab Coal Convers, Inst Coal Chem, South Taoyuan Rd 27, Taiyuan 030001, Shanxi, Peoples R China

来源：

SYNTHESIS-STUTTGART | 2019年 / 51卷 / 03期

基金：

中国国家自然科学基金;

关键词：

carbon dioxide utilization; carbonates; zinc catalysis; multicomponent reaction; synthetic methods; PROPARGYLIC ALCOHOLS; ORGANIC CARBONATES; CHEMICAL FIXATION; DIOXIDE; EFFICIENT; CYCLOADDITION; EPOXIDES; SYSTEM; STRATEGIES; CARBAMATE;

D O I：

10.1055/s-0037-1611058

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

It is promising and challenging to achieve the effective construction of carbonates using CO2 and a non-noble metal catalyst. Herein, selective catalytic conversion of CO2 and switchable alcohol candidates to produce linear or cyclic carbonates and alpha-hydroxy ketones via effective zinc catalyst was developed. A series of primary alcohols and cyclohexanol, 1,2-diols, and water can serve as nucleophiles to give alkyl or aryl 2-substituted-3-oxobutan-2-yl carbonates, substituted 1,3-dioxolan-2-ones, 3-substituted 3-hydroxybutan-2-ones, respectively with excellent selectivity and high yields.

引用

页码：739 / 746

页数：8

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