Microporous Polymeric Spheres as Highly Efficient and Metal-Free Catalyst for the Cycloaddition of CO2 to Cyclic Organic Carbonates at Ambient Conditions

被引：11
|
作者：
Ding, Shunmin [1 ]
Sun, Ling [1 ]
Ma, Xiaohua [1 ]
Cheng, Dan [1 ]
Wu, Shaohua [1 ]
Zeng, Rong [2 ]
Deng, Shengjun [1 ]
Chen, Chao [1 ]
Zhang, Ning [1 ]
机构：
[1] Nanchang Univ, Coll Chem, Key Lab Jiangxi Prov Environm & Energy Catalysis, Nanchang 330031, Jiangxi, Peoples R China
[2] East China Univ Technol, Sch Chem Biol & Mat Sci, Jiangxi Prov Key Lab Polymer Micro Nano Mfg & Dev, Nanchang 330013, Jiangxi, Peoples R China
来源：
CATALYSIS LETTERS | 2020年 / 150卷 / 10期
基金：
中国国家自然科学基金;
关键词：
Carbon dioxide; Cyclic organic carbonates; Heterogeneous catalysis; Microporous polymeric spheres; Metal-free; DIOXIDE UTILIZATION; IONIC LIQUID; HETEROGENEOUS CATALYSTS; BIFUNCTIONAL CATALYST; EPOXIDES; FIXATION; FRAMEWORK; CAPTURE; CAGES; OXIDE;
D O I：
10.1007/s10562-020-03206-y
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The cycloaddition of CO2 with epoxides to cyclic organic carbonates using metal-free heterogeneous catalysts is considered as a 100% atom-economic and environmental-friendly route for CO2 utilization. Herein, we developed a metal-free microporous polymeric spheres catalyst (p-TBIB) by a simple Friedel-Crafts alkylation and applied in the cycloaddition of CO2 to cyclic organic carbonates. The catalyst shows high CO2 uptake (62.7 cm(3) g(-1), at 298 K and 1 bar), high selectivity over N-2 (46 at 298 K) and perfect cycloaddition activities (66-97%) and selectivities (over 99%) and reusability (at least ten cycles) at ambient conditions (at 298 K and 1 bar). [GRAPHICS] .
引用
收藏
页码：2970 / 2977
页数：8
相关论文
共 50 条
  • [41] Metal-Free Catalytic Formylation of Amides Using CO2 under Ambient Conditions
    Hota, Pradip Kumar
    Sau, Samaresh Chandra
    Mandal, Swadhin K.
    ACS CATALYSIS, 2018, 8 (12): : 11999 - 12003
  • [42] Multi-functionalization of GO with multi-cationic ILs as high efficient metal-free catalyst for CO2 cycloaddition under mild conditions
    Lan, Dong-Hui
    Gong, Yan-Xi
    Tan, Nian-Yuan
    Wu, Shui-Sheng
    Shen, Jing
    Yao, Kui-Cheng
    Yi, Bing
    Au, Chak-Tong
    Yin, Shuang-Feng
    CARBON, 2018, 127 : 245 - 254
  • [43] Robust multivariate metal-porphyrin frameworks for efficient ambient fixation of CO2 to cyclic carbonates
    He, Liang
    Nath, Jayanta Kumar
    Lin, Qipu
    CHEMICAL COMMUNICATIONS, 2019, 55 (03) : 412 - 415
  • [44] Microporous organic networks bearing metal-salen species for mild CO2 fixation to cyclic carbonates
    Chun, Jiseul
    Kang, Sungah
    Kang, Narae
    Lee, Sang Moon
    Kim, Hae Jin
    Son, Seung Uk
    JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (18) : 5517 - 5523
  • [45] A highly stable MnII phosphonate as a highly efficient catalyst for CO2 fixation under ambient conditions
    Yang, Yang
    Gao, Chao-Ying
    Tian, Hong-Rui
    Ai, Jing
    Min, Xue
    Sun, Zhong-Ming
    CHEMICAL COMMUNICATIONS, 2018, 54 (14) : 1758 - 1761
  • [46] Core–Shell Dispersed Polymeric Ionic Liquids as Efficient Heterogeneous Catalyst for CO2 Conversion into Cyclic Carbonates
    Shuaifei Liu
    Qian Su
    Mengqian Fu
    Lili Deng
    Yichao Wang
    Li Dong
    Yifan Liu
    Xinqi Ma
    Weiguo Cheng
    Catalysis Letters, 2023, 153 : 2429 - 2442
  • [47] Self-nitrogen-doped hierarchical porous carbon spheres as metal-free catalyst for efficient photocatalytic CO2 reduction
    Wang, Yuan
    Xu, Guomin
    Xue, Chao
    Zhang, Changming
    Xue, Jinbo
    Zhang, Xiaochao
    SEPARATION AND PURIFICATION TECHNOLOGY, 2024, 342
  • [48] Ni(salphen)-based metal-organic framework for the synthesis of cyclic carbonates by cycloaddition of CO2 to epoxides
    Ren, Yanwei
    Shi, Yanchao
    Chen, Junxian
    Yang, Shaorong
    Qi, Chaorong
    Jiang, Huanfeng
    RSC ADVANCES, 2013, 3 (07): : 2167 - 2170
  • [49] Novel Cobalt Complex as an Efficient Catalyst for Converting CO2 into Cyclic Carbonates under Mild Conditions
    Fan, Wei
    Wang, Wen-Zhen
    Wang, Li
    Jia, Xin-Gang
    Li, Lei-Lei
    Xiao, Tian-Cun
    Edwards, Peter P.
    CATALYSTS, 2019, 9 (11)
  • [50] An efficient ternary catalyst ZnBr2/K2CO3/[Bmim]Br for chemical fixation of CO2 into cyclic carbonates at ambient conditions
    Zhang, Huizi
    Kong, Xianqiang
    Cao, Changsheng
    Pang, Guangsheng
    Shi, Yanhui
    JOURNAL OF CO2 UTILIZATION, 2016, 14 : 76 - 82
12345