Microporous Polymeric Spheres as Highly Efficient and Metal-Free Catalyst for the Cycloaddition of CO2 to Cyclic Organic Carbonates at Ambient Conditions

被引：11
|
作者：
Ding, Shunmin [1 ]
Sun, Ling [1 ]
Ma, Xiaohua [1 ]
Cheng, Dan [1 ]
Wu, Shaohua [1 ]
Zeng, Rong [2 ]
Deng, Shengjun [1 ]
Chen, Chao [1 ]
Zhang, Ning [1 ]
机构：
[1] Nanchang Univ, Coll Chem, Key Lab Jiangxi Prov Environm & Energy Catalysis, Nanchang 330031, Jiangxi, Peoples R China
[2] East China Univ Technol, Sch Chem Biol & Mat Sci, Jiangxi Prov Key Lab Polymer Micro Nano Mfg & Dev, Nanchang 330013, Jiangxi, Peoples R China
来源：
CATALYSIS LETTERS | 2020年 / 150卷 / 10期
基金：
中国国家自然科学基金;
关键词：
Carbon dioxide; Cyclic organic carbonates; Heterogeneous catalysis; Microporous polymeric spheres; Metal-free; DIOXIDE UTILIZATION; IONIC LIQUID; HETEROGENEOUS CATALYSTS; BIFUNCTIONAL CATALYST; EPOXIDES; FIXATION; FRAMEWORK; CAPTURE; CAGES; OXIDE;
D O I：
10.1007/s10562-020-03206-y
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The cycloaddition of CO2 with epoxides to cyclic organic carbonates using metal-free heterogeneous catalysts is considered as a 100% atom-economic and environmental-friendly route for CO2 utilization. Herein, we developed a metal-free microporous polymeric spheres catalyst (p-TBIB) by a simple Friedel-Crafts alkylation and applied in the cycloaddition of CO2 to cyclic organic carbonates. The catalyst shows high CO2 uptake (62.7 cm(3) g(-1), at 298 K and 1 bar), high selectivity over N-2 (46 at 298 K) and perfect cycloaddition activities (66-97%) and selectivities (over 99%) and reusability (at least ten cycles) at ambient conditions (at 298 K and 1 bar). [GRAPHICS] .
引用
收藏
页码：2970 / 2977
页数：8
相关论文
共 50 条
  • [31] Engineering noble-metal-free metal-organic framework composite catalyst for efficient CO2 conversion under ambient conditions
    Cui, Hui-Ya
    Zhang, Ya-Xin
    Cao, Chun-Shuai
    Hu, Tian-Ding
    Wu, Zhi-Lei
    CHEMICAL ENGINEERING JOURNAL, 2023, 451
  • [32] Metal-Free Amine-Anchored Triazine-Based Covalent Organic Polymers for Selective CO2 Adsorption and Conversion to Cyclic Carbonates Under Mild Conditions
    Ravi, Seenu
    Kim, Jinwoo
    Choi, Yujin
    Han, Hyug Hee
    Wu, Shiliang
    Xiao, Rui
    Bae, Youn-Sang
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2023, 11 (03) : 1190 - 1199
  • [33] Polymeric Ionic Liquid Grafted on Silica for Efficient Conversion of CO2 into Cyclic Carbonates
    Ying, Ting
    Su, Qian
    Shi, Zijie
    Deng, Lili
    Cheng, Weiguo
    Hua, Wei
    CATALYSIS LETTERS, 2019, 149 (10) : 2647 - 2655
  • [34] Solvent-free cycloaddition of CO2 and propylene oxide to cyclic carbonates using different ligand metal complexes
    Narang, Shilpa
    Mehta, Rajeev
    Upadhyay, S. N.
    INORGANIC AND NANO-METAL CHEMISTRY, 2017, 47 (06) : 909 - 916
  • [35] A highly efficient zeolitic imidazolate framework catalyst for the co-catalyst and solvent free synthesis of cyclic carbonates from CO2
    Hwang, Gyu-Young
    Roshan, Roshith
    Ryu, Hyeong-Seok
    Jeong, Hye-Min
    Ravi, Seenu
    Kim, Moon-Il
    Park, Dae-Won
    JOURNAL OF CO2 UTILIZATION, 2016, 15 : 123 - 130
  • [36] Metal-Free Catalytic Formylation of Amides Using CO2 under Ambient Conditions
    Hota, Pradip Kumar
    Sau, Samaresh Chandra
    Mandal, Swadhin K.
    ACS CATALYSIS, 2018, 8 (12): : 11999 - 12003
  • [37] A novel conjugated microporous polymer microspheres comprising cobalt porphyrins for efficient catalytic CO2 cycloaddition under ambient conditions
    Zhang, Xiaofeng
    Wang, Junhong
    Bian, Yunpeng
    Lv, Huijuan
    Qiu, Bo
    Zhang, Yuanyuan
    Qin, Ruiyuan
    Zhu, Dandan
    Zhang, Sheng
    Li, Dajian
    Wang, Shimin
    Mai, Wenpeng
    Li, Yue
    Li, Tao
    JOURNAL OF CO2 UTILIZATION, 2022, 58
  • [38] Triazole Appended Metal-Organic Framework for CO2 Fixation as Cyclic Carbonates Under Solvent-Free Ambient Conditions
    Helal, Aasif
    Zahir, Md Hasan
    Albadrani, Ahmed
    Ekhwan, Moayad Mohammed
    CATALYSIS LETTERS, 2023, 153 (10) : 2883 - 2891
  • [39] Superbase/saccharide: An ecologically benign catalyst for efficient fixation of CO2 into cyclic carbonates
    Cheng, Weiguo
    Xu, Fei
    Sun, Jian
    Dong, Kun
    Ma, Congkai
    Zhang, Suojiang
    SYNTHETIC COMMUNICATIONS, 2016, 46 (06) : 497 - 508
  • [40] Green synthesized cobalt-bipyridine constructed conjugated microporous polymer: An efficient heterogeneous catalyst for cycloaddition of epoxides via CO2 fixation under ambient conditions
    Zhang, Xiaofeng
    Qiu, Bo
    Zou, Yu
    Wang, Shimin
    Mai, Wenpeng
    Cao, Yi
    Wang, Yanwei
    Chen, Jian
    Li, Tao
    MICROPOROUS AND MESOPOROUS MATERIALS, 2021, 319
12345