Microporous Polymeric Spheres as Highly Efficient and Metal-Free Catalyst for the Cycloaddition of CO2 to Cyclic Organic Carbonates at Ambient Conditions

被引：11

作者：

Ding, Shunmin ^{[1
]}

Sun, Ling ^{[1
]}

Ma, Xiaohua ^{[1
]}

Cheng, Dan ^{[1
]}

Wu, Shaohua ^{[1
]}

Zeng, Rong ^{[2
]}

Deng, Shengjun ^{[1
]}

Chen, Chao ^{[1
]}

Zhang, Ning ^{[1
]}

机构：

[1] Nanchang Univ, Coll Chem, Key Lab Jiangxi Prov Environm & Energy Catalysis, Nanchang 330031, Jiangxi, Peoples R China

[2] East China Univ Technol, Sch Chem Biol & Mat Sci, Jiangxi Prov Key Lab Polymer Micro Nano Mfg & Dev, Nanchang 330013, Jiangxi, Peoples R China

来源：

CATALYSIS LETTERS | 2020年 / 150卷 / 10期

基金：

中国国家自然科学基金;

关键词：

Carbon dioxide; Cyclic organic carbonates; Heterogeneous catalysis; Microporous polymeric spheres; Metal-free; DIOXIDE UTILIZATION; IONIC LIQUID; HETEROGENEOUS CATALYSTS; BIFUNCTIONAL CATALYST; EPOXIDES; FIXATION; FRAMEWORK; CAPTURE; CAGES; OXIDE;

D O I：

10.1007/s10562-020-03206-y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The cycloaddition of CO2 with epoxides to cyclic organic carbonates using metal-free heterogeneous catalysts is considered as a 100% atom-economic and environmental-friendly route for CO2 utilization. Herein, we developed a metal-free microporous polymeric spheres catalyst (p-TBIB) by a simple Friedel-Crafts alkylation and applied in the cycloaddition of CO2 to cyclic organic carbonates. The catalyst shows high CO2 uptake (62.7 cm(3) g(-1), at 298 K and 1 bar), high selectivity over N-2 (46 at 298 K) and perfect cycloaddition activities (66-97%) and selectivities (over 99%) and reusability (at least ten cycles) at ambient conditions (at 298 K and 1 bar). [GRAPHICS] .

引用

页码：2970 / 2977

页数：8

共 50 条

[21] Trifunctional Metal-Organic Framework Catalyst for CO2 Conversion into Cyclic Carbonates
Liu, Shuo
Gao, Ming-Liang
Zhang, Yue
Liu, Lin
Han, Zheng-Bo
INORGANIC CHEMISTRY, 2021, 60 (09) : 6152 - 6156
[22] Novel Cobalt Complex as an Efficient Catalyst for Converting CO2 into Cyclic Carbonates under Mild Conditions
Fan, Wei
Wang, Wen-Zhen
Wang, Li
Jia, Xin-Gang
Li, Lei-Lei
Xiao, Tian-Cun
Edwards, Peter P.
CATALYSTS, 2019, 9 (11)
[23] Direct Catalytic Conversion of CO2 to Cyclic Organic Carbonates under Mild Reaction Conditions by Metal-Organic Frameworks
Huh, Seong
CATALYSTS, 2019, 9 (01)
[24] An efficient ternary catalyst ZnBr2/K2CO3/[Bmim]Br for chemical fixation of CO2 into cyclic carbonates at ambient conditions
Zhang, Huizi
Kong, Xianqiang
Cao, Changsheng
Pang, Guangsheng
Shi, Yanhui
JOURNAL OF CO2 UTILIZATION, 2016, 14 : 76 - 82
[25] Magnesium-porphyrin as an efficient photocatalyst for the transformation of CO2 to cyclic carbonates and oxazolidinones under ambient conditions
Meher, Sushanta Kumar
Nayak, Prakash
Dhala, Sasmita
Tripathy, Swetapadma
Venkatasubbaiah, Krishnan
CATALYSIS SCIENCE & TECHNOLOGY, 2024, 14 (11) : 3125 - 3130
[26] Highly efficient cycloaddition of diluted and waste CO2 into cyclic carbonates catalyzed by porous ionic copolymers
Hui, Wei
He, Xue-Mei
Xu, Xin-Yi
Chen, Yue-Miao
Zhou, Yan
Li, Zhang-Min
Zhang, Liqi
Tao, Duan-Jian
JOURNAL OF CO2 UTILIZATION, 2020, 36 : 169 - 176
[27] Metal-Free Synthesis of Cyclic and Acyclic Carbonates from CO2 and Alcohols
Lim, Yu Na
Lee, Chan
Jang, Hye-Young
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2014, 2014 (09) : 1823 - 1826
[28] Facile construction of bifunctional porous ionic polymers for efficient and metal-free catalytic conversion of CO2 into cyclic carbonates
Wan, Ya-Li
Zhang, Zemin
Ding, Chao
Wen, Lili
JOURNAL OF CO2 UTILIZATION, 2021, 52
[29] A Copper Metal-Organic Hydrogel as a Catalyst for SO2 and CO2 Fixation under Ambient Conditions
Karan, Chandane Kumar
Bhattacharjee, Manish
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 2019 (31) : 3605 - 3611
[30] Recent advances in metal-free catalysts for the synthesis of cyclic carbonates from CO2 and epoxides
Lan, Dong-Hui
Fan, Na
Wang, Ying
Gao, Xian
Zhang, Ping
Chen, Lang
Au, Chak-Tong
Yin, Shuang-Feng
CHINESE JOURNAL OF CATALYSIS, 2016, 37 (06) : 826 - 845

← 1 2 3 4 5 →