Microporous Polymeric Spheres as Highly Efficient and Metal-Free Catalyst for the Cycloaddition of CO2 to Cyclic Organic Carbonates at Ambient Conditions

被引：11
|
作者：
Ding, Shunmin [1 ]
Sun, Ling [1 ]
Ma, Xiaohua [1 ]
Cheng, Dan [1 ]
Wu, Shaohua [1 ]
Zeng, Rong [2 ]
Deng, Shengjun [1 ]
Chen, Chao [1 ]
Zhang, Ning [1 ]
机构：
[1] Nanchang Univ, Coll Chem, Key Lab Jiangxi Prov Environm & Energy Catalysis, Nanchang 330031, Jiangxi, Peoples R China
[2] East China Univ Technol, Sch Chem Biol & Mat Sci, Jiangxi Prov Key Lab Polymer Micro Nano Mfg & Dev, Nanchang 330013, Jiangxi, Peoples R China
来源：
CATALYSIS LETTERS | 2020年 / 150卷 / 10期
基金：
中国国家自然科学基金;
关键词：
Carbon dioxide; Cyclic organic carbonates; Heterogeneous catalysis; Microporous polymeric spheres; Metal-free; DIOXIDE UTILIZATION; IONIC LIQUID; HETEROGENEOUS CATALYSTS; BIFUNCTIONAL CATALYST; EPOXIDES; FIXATION; FRAMEWORK; CAPTURE; CAGES; OXIDE;
D O I：
10.1007/s10562-020-03206-y
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The cycloaddition of CO2 with epoxides to cyclic organic carbonates using metal-free heterogeneous catalysts is considered as a 100% atom-economic and environmental-friendly route for CO2 utilization. Herein, we developed a metal-free microporous polymeric spheres catalyst (p-TBIB) by a simple Friedel-Crafts alkylation and applied in the cycloaddition of CO2 to cyclic organic carbonates. The catalyst shows high CO2 uptake (62.7 cm(3) g(-1), at 298 K and 1 bar), high selectivity over N-2 (46 at 298 K) and perfect cycloaddition activities (66-97%) and selectivities (over 99%) and reusability (at least ten cycles) at ambient conditions (at 298 K and 1 bar). [GRAPHICS] .
引用
收藏
页码：2970 / 2977
页数：8
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