Synthesis and characterizaion of a new inorganic-organic sulfate compound -: Crystal structure of [Ni(H2O)6][H2N(C2H4)2NH2](SO4)2

被引：0

作者：

Meng, H ^{[1
]}

Xing, Y ^{[1
]}

Fu, YL ^{[1
]}

Shi, Z ^{[1
]}

Pang, WQ ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China

来源：

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 2004年 / 20卷 / 01期

关键词：

inorganic-organic compound; crystal structure; nickel sulfate;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Ni(H2O)(6)][H2N(C2H4)(2)NH2](SO4)(2) is an inorganic-organic compound with a new open framework synthesized by hydrothermal method, and characterized by means of single-crystal diffraction and spectroscopic data. The compound crystallized in a monoclinic space group P2(1)/n with a = 1.29089(2) nm. b = 1.06301(3) nm. c = 1.33202(4) nm, beta = 114.0870(10)degrees, V = 1.67127(8) nm(3), Z = 4, and was solved by using the direct method and the least-squares refinement converged at R = 0.0214[I>2sigma(I)]. The structure consists of isolated Ni(H2O)(6) octahedra and SO4 tetrahedra, with both of them hydrogen-bonded to piperazine cations.

引用

页码：1 / 5

页数：5

共 15 条

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