A nickel/organoboron catalyzed metallaphotoredox platform for C(sp2)-P and C(sp2)-S bond construction

被引：17
|
作者：
Zhu, Yuan [1 ]
Zu, Weisai [1 ]
Tian, Qing [1 ]
Cao, Zifeng [1 ]
Wei, Yu [1 ]
Xu, Liang [1 ]
机构：
[1] Shihezi Univ, Sch Chem & Chem Engn, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, Shihezi 832003, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2022年 / 9卷 / 04期
基金：
中国国家自然科学基金;
关键词：
VISIBLE-LIGHT PHOTOREDOX; NICKEL CATALYSIS; CARBON; ARYL; THIOLS; OXYGEN;
D O I：
10.1039/d1qo01778k
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Herein, an organoboron photocatalyst, aminoquinolate diarylboron (AQDAB), is utilized collaboratively with a nickel catalyst in metallaphotoredox catalyzed C(sp(2))-P and C(sp(2))-S cross-coupling reactions. This strategy effectively couples aryl halides with diarylphosphine oxides and thiols at room temperature under an air atmosphere, affording the corresponding triarylphosphine oxides and thioethers in generally moderate to good yields.
引用
收藏
页码：1070 / 1076
页数：7
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