Origin of strong correlations and superconductivity in NaxCoO2

被引:21
作者
Khaliullin, Giniyat [1 ]
Chaloupka, Jiri [1 ,2 ]
机构
[1] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany
[2] Masaryk Univ, Fac Sci, Dept Condensed Matter Phys, CS-61137 Brno, Czech Republic
关键词
D O I
10.1103/PhysRevB.77.104532
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We propose a minimal model resolving a puzzle of enigmatic correlations observed in sodium-rich NaxCoO2 where one expects a simple, free motion of the dilute S= 1/2 holes doped into a band insulator NaCoO2. The model also predicts singlet superconductivity at experimentally observed compositions. The model is based on a key property of cobalt oxides-the spin-state quasidegeneracy of CoO6 octahedral complex-leading to an unusual physics of, e. g., LaCoO3. We show that correlated hopping between t(2g) and e(g) states leads to the spin-polaron physics at x similar to 1, and to an extended s-wave pairing at larger doping when coherent fermionic bands are formed.
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页数:6
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