Interfacial Photoreduction of Supercritical CO2 by an Aqueous Catalyst

被引：58

作者：

Mendez, Manuel A. ^{[1
]}

Voyame, Patrick ^{[1
]}

Girault, Hubert H. ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Lab Electrochim Phys & Analyt, Stn 6, CH-1015 Lausanne, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 32期

关键词：

adsorption; carbon dioxide; cyclam; photochemistry; supercritical fluids; CARBON-DIOXIDE; PHOTOCHEMICAL REDUCTION; LIQUID/LIQUID INTERFACES; PHOTOCATALYTIC REDUCTION; NICKEL(II) CYCLAM; OXYGEN REDUCTION; VISIBLE-LIGHT; WATER; COMPLEXES; COBALT;

D O I：

10.1002/anie.201100828

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Not just a solvent anymore: CO2 reduction under supercritical conditions was achieved in a biphasic water-supercritical CO2 system using an aqueous soluble catalyst (see picture). The introduction of such an interface provides a suitable reaction medium where adsorption, CO2 binding, and protonation of intermediates are intimately linked. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7391 / 7394

页数：4

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