Metallosiloxanes containing period 5 transition metals: synthesis and X-ray studies of three cadmium siloxanes

被引:15
作者
Sergienko, Natalia V. [1 ]
Korlyukov, Alexander A. [1 ]
Arkhipov, Dmitry E. [1 ]
Novikov, Valentin V. [1 ]
Eskova, Marina A. [1 ]
Zavin, Boris G. [1 ]
机构
[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia
基金
俄罗斯科学基金会;
关键词
COMPLEXES; LIGANDS; NICKEL;
D O I
10.1016/j.mencom.2016.07.026
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hydrolysis of PhSi(OEt)(3) in the presence of MOH (M = K, Na) and CdBr2 affords new cadmium siloxanes of sandwich type, whose encapsulated species (Br-, H2O, OH) are defined by the solvent used for synthesis and crystallization.
引用
收藏
页码:344 / 346
页数:3
相关论文
共 12 条
[1]   The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].
Allen, FH .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388
[2]   New heterometallic organosiloxanes [J].
Bilyachenko, A. N. ;
Sergienko, N. V. ;
Korlyukov, A. A. ;
Antipin, M. Yu. ;
Zavin, B. G. ;
Levitskii, M. M. .
RUSSIAN CHEMICAL BULLETIN, 2006, 55 (05) :943-945
[3]   Cage-like Copper(II) Silsesquioxanes: Transmetalation Reactions and Structural, Quantum Chemical, and Catalytic Studies [J].
Bilyachenko, Alexey N. ;
Dronova, Marina S. ;
Yalymov, Alexey I. ;
Lamaty, Frederic ;
Bantreil, Xavier ;
Martinez, Jean ;
Bizet, Christelle ;
Shul'pina, Lidia S. ;
Korlyukov, Alexander A. ;
Arkhipov, Dmitry E. ;
Levitsky, Mikhail M. ;
Shubina, Elena S. ;
Kirillov, Alexander M. ;
Shul'pin, Georgiy B. .
CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (24) :8758-8770
[4]   OLEX2: a complete structure solution, refinement and analysis program [J].
Dolomanov, Oleg V. ;
Bourhis, Luc J. ;
Gildea, Richard J. ;
Howard, Judith A. K. ;
Puschmann, Horst .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2009, 42 :339-341
[5]   NOVEL CLASS OF TRANSITION-METAL COORDINATION-COMPOUNDS WITH MACROCYCLIC ORGANOSILOXANOLATE LIGANDS, THEIR SYNTHESIS AND CRYSTAL-STRUCTURE [J].
IGONIN, VA ;
SHCHEGOLIKHINA, OI ;
LINDEMAN, SV ;
LEVITSKY, MM ;
STRUCHKOV, YT ;
ZHDANOV, AA .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 423 (03) :351-360
[6]  
IGONIN VA, 1991, ORGANOMET CHEM USSR, V4, P383
[7]   Heteroligand nickel siloxane with 4-vinylbenzyl substituents [J].
Korlyukov, Alexander A. ;
Eskova, Marina A. ;
Tkachenko, Igor M. ;
Kononevich, Yuriy N. ;
Shchegolikhina, Olga I. ;
Muzafarov, Aziz M. .
MENDELEEV COMMUNICATIONS, 2015, 25 (03) :226-228
[8]   Modern concepts and methods in the chemistry of polyhedral metallasiloxanes [J].
Levitsky, Mikhail M. ;
Bilyachenko, Alexey N. .
COORDINATION CHEMISTRY REVIEWS, 2016, 306 :235-269
[9]   Synthesis and study of the structure of cage-like metallosiloxanes with pair combinations of 3d transition and alkaline earth metals [J].
Sergienko, N. V. ;
Cherkun, N. V. ;
Korlyukov, A. A. ;
Sochikhin, A. A. ;
Myakushev, V. D. ;
Strelkova, T. V. ;
Zavin, B. G. .
RUSSIAN CHEMICAL BULLETIN, 2013, 62 (09) :1999-2006
[10]   REVISED EFFECTIVE IONIC-RADII AND SYSTEMATIC STUDIES OF INTERATOMIC DISTANCES IN HALIDES AND CHALCOGENIDES [J].
SHANNON, RD .
ACTA CRYSTALLOGRAPHICA SECTION A, 1976, 32 (SEP1) :751-767