rare earth compounds;
transition metal compounds;
anisotropy;
magnetic measurements;
D O I:
10.1016/S0925-8388(01)01174-4
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
A single crystal of Sm6Fe23 was prepared by means of a modified self-flux method, and its crystallographic magnetic properties were studied. Sm6Fe23 has the cubic Th6Mn23-type structure (space group Fm3m) with a lattice constant of a = 1.2187 +/-0.0006 nm. The easy axis of magnetization is parallel to the < 111 > direction. Its magnetic moment per unit formula deduced from the saturation magnetization is 59 mu (B) at 5 K, a value that is consistent with the value calculated assuming ferromagnetic coupling between the Sm and Fe sublattices. The cubic anisotropy constants K, and K, estimated from the magnetization curves of the [111], [110], and [100] directions are -2.7 x 10(6) and 6.3x10(5) erg/cm(3), respectively, The anisotropy field H-A calculated from the anisotropy constants is 6.1 kOe. (C) 2001 Elsevier Science B.V. All rights reserved.
机构:
Univ Tunis El Manar, Fac Sci Tunis, Lab Mat Org & Proprietes, Tunis 2092, TunisiaUniv Tunis El Manar, Fac Sci Tunis, Lab Mat Org & Proprietes, Tunis 2092, Tunisia
Fersi, R.
Dalia, A. P.
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机构:
Dept Mat Sci & Engn, 313 Splaiul Unirii St, Bucharest 020745, RomaniaUniv Tunis El Manar, Fac Sci Tunis, Lab Mat Org & Proprietes, Tunis 2092, Tunisia
机构:
Acad Sinica, Inst Met Res, Int Ctr Mat Phys, Shenyang 110015, Peoples R ChinaAcad Sinica, Inst Met Res, Int Ctr Mat Phys, Shenyang 110015, Peoples R China
Geng, DY
Zhang, ZD
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机构:Acad Sinica, Inst Met Res, Int Ctr Mat Phys, Shenyang 110015, Peoples R China
Zhang, ZD
Liu, W
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机构:Acad Sinica, Inst Met Res, Int Ctr Mat Phys, Shenyang 110015, Peoples R China
Liu, W
Zhao, XG
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机构:Acad Sinica, Inst Met Res, Int Ctr Mat Phys, Shenyang 110015, Peoples R China
Zhao, XG
You, CY
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机构:Acad Sinica, Inst Met Res, Int Ctr Mat Phys, Shenyang 110015, Peoples R China
You, CY
Yu, MH
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机构:Acad Sinica, Inst Met Res, Int Ctr Mat Phys, Shenyang 110015, Peoples R China
Yu, MH
Xiao, QF
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机构:Acad Sinica, Inst Met Res, Int Ctr Mat Phys, Shenyang 110015, Peoples R China
Xiao, QF
Grössinger, R
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机构:Acad Sinica, Inst Met Res, Int Ctr Mat Phys, Shenyang 110015, Peoples R China
Grössinger, R
Liu, JP
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机构:Acad Sinica, Inst Met Res, Int Ctr Mat Phys, Shenyang 110015, Peoples R China
机构:
Hebei Univ Technol, Key Lab New Type Funct Mat Hebei Prov, Sch Mat Sci & Engn, 8,Rd 1, Tianjin 300130, Peoples R ChinaHebei Univ Technol, Key Lab New Type Funct Mat Hebei Prov, Sch Mat Sci & Engn, 8,Rd 1, Tianjin 300130, Peoples R China
Kang, Licong
Cui, Chunxiang
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机构:
Hebei Univ Technol, Key Lab New Type Funct Mat Hebei Prov, Sch Mat Sci & Engn, 8,Rd 1, Tianjin 300130, Peoples R ChinaHebei Univ Technol, Key Lab New Type Funct Mat Hebei Prov, Sch Mat Sci & Engn, 8,Rd 1, Tianjin 300130, Peoples R China
Cui, Chunxiang
Yang, Wei
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机构:
Hebei Univ Technol, Key Lab New Type Funct Mat Hebei Prov, Sch Mat Sci & Engn, 8,Rd 1, Tianjin 300130, Peoples R ChinaHebei Univ Technol, Key Lab New Type Funct Mat Hebei Prov, Sch Mat Sci & Engn, 8,Rd 1, Tianjin 300130, Peoples R China
Yang, Wei
Guo, Jing
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机构:
Hebei Univ Technol, Key Lab New Type Funct Mat Hebei Prov, Sch Mat Sci & Engn, 8,Rd 1, Tianjin 300130, Peoples R ChinaHebei Univ Technol, Key Lab New Type Funct Mat Hebei Prov, Sch Mat Sci & Engn, 8,Rd 1, Tianjin 300130, Peoples R China