The reactions of gallium metal with (p-MeOC(6)H(4))(3)AsI2 and Et(3)AsI(2); Isolation of a novel gallium(II) arsine complex with a gallium-gallium bond and the X-ray crystal structures of GaI3[(p-MeOC(6)H(4))(3)As] and Ga2I4(AsEt(3))(2)

被引：20

作者：

Beagley, B

Godfrey, SM

Kelly, KJ

Kungwankunakorn, S

McAuliffe, CA

Pritchard, RG

机构：

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 18期

关键词：

D O I：

10.1039/cc9960002179

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of (p-MeOC(6)H(4))(3)AsI2 and Et(3)AsI(2) with gallium metal powder produce the metal complexes GaI3[(p-MeOC(6)H(4))(3)As] and Ga2I4(AsEt(3))(2), respectively; the latter represents a unique example of a gallium-tertiary arsine complex containing a gallium-gallium bond, and both structures illustrate the subtle effect of the organic substituent on the arsenic atoms.

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页码：2179 / 2180

页数：2

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