Effects of Gd-Substitutions on the Microstructure, Electrical and Electromagnetic Behavior of M-Type Hexagonal Ferrites

A series of Gd-substituted Ba-Co-based (M-type) hexaferrites having the chemical compositions of Ba0.5Co0.5Gd (x) Fe12-x O-19 (x = 0.0, 0.2, 0.4, 0.6, 0.8, 1.0) were prepared by co-precipitation method. The pellets formed by co-precipitated powder were calcined at a temperature of 1200A degrees C for 20 h. Final sintering was done at 1320A degrees C for 4 h. From the x-ray diffraction analysis, it was revealed that all the samples showed M-type hexagonal structure as a major phase. The scanning electron microscope was used to examine the morphology of the sintered ferrites. The average grain size estimated by the line intercept method was found to be in the range of 2.8-1.0 mu m. The room temperature DC resistivity increases with increasing Gd-contents to make these ferrites useful for high frequency applications and microwave devices. Lower values of coercivity (H (c)) and higher saturation magnetization (M (s)) may be suitable to enhance the permeability of these ferrites, which is favorable for impedance matching in microwave absorption. In addition, reflection coefficients for a sample was also measured from a frequency of 1 MHz to 3 GHz and a reflection peak was observed at about 2.2 GHz.