Mixed ligand (acetylacetonato)(chlorophenoxo)zirconium(IV) complexes and their reactivity

被引：0

作者：

Bhatt, SS ^{[1
]}

Kumari, R ^{[1
]}

Sharma, N ^{[1
]}

Chaudhry, SC ^{[1
]}

机构：

[1] Himachal Pradesh Univ, Dept Chem, Shimla 171005, Himachal Prades, India

来源：

JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2005年 / 82卷 / 04期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zr-IV complexes of composition ZrCl2-n (acac)(2)(OArI,II) where n = 1, 2, acac = -C5H7O2 (acetylacetonate anion), OAr1 = OC6H4-Cl-o and OArII = OC6H4-Cl-p have been prepared and characterized by elemental analyses, molecular weight, molar conductance, IR and H-1 NMR data. The donor complexes, ZrCl(acac)(2)(OArI,II) react with Lewis acids (FeCl3 and PCl5) in nitrobenzene at 25 +/- 1 degrees C to produce [Zr(acac)(2)(OArI,II)](+)[FeCl4](-) and [Zr(acac)(2)(OArI,II)](+)[PCl6](-).

引用

页码：354 / 356

页数：3

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