Polymers from Biobased-Monomers: Macroporous Itaconic Xerogels Prepared in Deep Eutectic Solvents

被引：11
作者：
Bednarz, Szczepan [1 ]
Wesolowska, Angelika [1 ]
Tratnowiecka, Magdalena [1 ]
Bogdal, Dariusz [1 ]
机构：
[1] Cracow Univ Technol, Dept Biotechnol & Phys Chem, Warszawska 24, PL-31155 Krakow, Poland
来源：
JOURNAL OF RENEWABLE MATERIALS | 2016年 / 4卷 / 01期
关键词：
Choline chloride; free-radical polymerization-crosslinking; hydrogels; phase segregation; renewable monomers; IONIC LIQUIDS; HYDROGELS; ACID; POLYMERIZATION; PRECURSORS; MONOLITHS; AGENTS;
D O I：
10.7569/JRM.2015.634131
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
New methods of preparation of crosslinked polymers from itaconic acid as a renewable monomer have been explored. Synthesis of hydrogels and xerogels from the acid in deep eutectic solvents (DESs) are described and some basic properties of the materials are reported. Most importantly, a surfactant-free method of creation of macroporous poly(itaconic-co-bisacrylamide) by phase separation polymerization in binary mixture of the DES and poly(ethylene glycol) is demonstrated.
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收藏
页码：18 / 23
页数：6
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共 26 条
  • [1] Preparation of novel, moisture-stable, Lewis-acidic ionic liquids containing quaternary ammonium salts with functional side chains
    Abbott, AP
    Capper, G
    Davies, DL
    Munro, HL
    Rasheed, RK
    Tambyrajah, V
    [J]. CHEMICAL COMMUNICATIONS, 2001, (19) : 2010 - 2011
  • [2] Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids
    Abbott, AP
    Boothby, D
    Capper, G
    Davies, DL
    Rasheed, RK
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (29) : 9142 - 9147
  • [3] Free-radical polymerization of itaconic acid in the presence of choline salts: Mechanism of persulfate decomposition
    Bednarz, Szczepan
    Blaszczyk, Alicja
    Blazejewska, Diana
    Bogdal, Dariusz
    [J]. CATALYSIS TODAY, 2015, 257 : 297 - 304
  • [4] Synthesis of Hydrogels by Polymerization of Itaconic Acid-Choline Chloride Deep Eutectic Solvent
    Bednarz, Szczepan
    Fluder, Maria
    Galica, Mateusz
    Bogdal, Dariusz
    Maciejaszek, Ireneusz
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2014, 131 (16)
  • [5] Characterization of pH-responsive hydrogels of poly(itaconic acid-g-ethylene glycol) prepared by UV-initiated free radical polymerization as biomaterials for oral delivery of bioactive agents
    Betancourt, Tania
    Pardo, Juan
    Soo, Ken
    Peppas, Nicholas A.
    [J]. JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A, 2010, 93A (01) : 175 - 188
  • [6] Deep-eutectic solvents as a support in the nonaqueous synthesis of macroporous poly(HIPEs)
    Carranza, A.
    Pojman, J. A.
    Mota-Morales, J. D.
    [J]. RSC ADVANCES, 2014, 4 (78): : 41584 - 41587
  • [7] Deep-eutectic solvents playing multiple roles in the synthesis of polymers and related materials
    Carriazo, Daniel
    Concepcion Serrano, Maria
    Concepcion Gutierrez, Maria
    Luisa Ferrer, Maria
    del Monte, Francisco
    [J]. CHEMICAL SOCIETY REVIEWS, 2012, 41 (14) : 4996 - 5014
  • [8] Resorcinol-Based Deep Eutectic Solvents as Both Carbonaceous Precursors and Templating Agents in the Synthesis of Hierarchical Porous Carbon Monoliths
    Carriazo, Daniel
    Gutierrez, Maria C.
    Luisa Ferrer, M.
    del Monte, Francisco
    [J]. CHEMISTRY OF MATERIALS, 2010, 22 (22) : 6146 - 6152
  • [9] Deep Eutectic Solvents in Polymerizations: A Greener Alternative to Conventional Syntheses
    del Monte, Francisco
    Carriazo, Daniel
    Serrano, Maria C.
    Gutierrez, Maria C.
    Luisa Ferrer, M.
    [J]. CHEMSUSCHEM, 2014, 7 (04) : 999 - 1009
  • [10] Structural analysis of dextran-based hydrogels obtained chemoenzymatically
    Ferreira, L
    Figueiredo, MM
    Gil, MH
    Ramos, MA
    [J]. JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART B-APPLIED BIOMATERIALS, 2006, 77B (01) : 55 - 64
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