Visible-light-promoted aerobic oxidative synthesis of β-ketosulfones under photocatalyst-free conditions

被引：22
|
作者：
Lv, Yufen [1 ]
Liu, Qishun [1 ]
Liu, Fei [1 ]
Yue, Huilan [2 ,3 ]
Li, Jiang-Sheng [4 ]
Wei, Wei [1 ,2 ,3 ]
机构：
[1] Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China
[2] Chinese Acad Sci, Northwest Inst Plateau Biol, Qinghai Prov Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China
[3] Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China
[4] Changsha Univ Sci & Technol, Sch Chem & Food Engn, Changsha 410114, Peoples R China
来源：
TETRAHEDRON LETTERS | 2020年 / 61卷 / 01期
关键词：
Visible-light; beta-ketosulfones; Alkynes; Photocatalyst-free; QUINOLINE N-OXIDES; INDUCED DEOXYGENATIVE C2-SULFONYLATION; SULFINIC ACIDS; ONE-POT; EFFICIENT APPROACH; HIGHLY EFFICIENT; KETO SULFONES; ALKENES; SULFONYLHYDRAZIDES; ALKYNES;
D O I：
10.1016/j.tetlet.2019.151335
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A simple and convenient visible-light-mediated method has been developed for the construction of beta-ketosulfones via aerobic oxidative difunctionalization of alkynes with arylazo sulfones and dioxygen in air under photocatalyst-free conditions. The present photochemical methodology provides a facile and attractive protocol to construct a series of beta-ketosulfones in moderate to good yields. (C) 2019 Elsevier Ltd. All rights reserved.
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页数：4
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