Diketopyrrolopyrrole-based conjugated polymers containing alkyl and aryl side-chains for bulk heterojunction solar cells

被引：2

作者：

Park, Su Jung ^{[1
]}

Jung, Ji Eun ^{[1
]}

Kang, Min Kwan ^{[1
]}

Na, Yang Ho ^{[1
]}

Song, Hyun Hoon ^{[1
]}

Kang, Jae Wook ^{[2
]}

Baek, Nam Seob ^{[3
]}

Kim, Tae-Dong ^{[1
]}

机构：

[1] Hannam Univ, Dept Adv Mat, Taejon 305811, South Korea

[2] Chonbuk Natl Univ, Polymer Mat Fus Res Ctr, Dept Flexible & Printable Elect, Jeonju 561756, South Korea

[3] Chem Opt Inc, Taejon 305510, South Korea

来源：

SYNTHETIC METALS | 2015年 / 203卷

基金：

新加坡国家研究基金会;

关键词：

DPP conjugated polymers; Side-chain engineering; Bulk heterojunction solar cells; THIN-FILM TRANSISTORS; ORGANIC PHOTOVOLTAICS; PERFORMANCE; MOBILITY; SEMICONDUCTORS; EFFICIENCY;

D O I：

10.1016/j.synthmet.2015.02.035

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A series of diketopyrrolopyrrole (DPP)-based conjugated polymers were synthesized with varied side groups such as alkyl and aryl side-chains on a DPP backbone. Their thermal, optical, and photovoltaic properties were investigated. After adding 2% of 1,8-diiodooctane (DIO) as a processing additive in active layers for the bulk heterojunction device, we could achieve the highest PCE of 2.02% with V-OC=0.68V, J(SC)=5.31 mA cm(-2), and FF=56.0% for PDPPT-s1:[70]PCBM (1:2). The device for PDPPT-as designed with asymmetrical side groups on the DPP units also showed good solar cell performance comparable with PDPPT-s1. These results suggest that the DIO additives can control side-chain interference on DPP units. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：221 / 227

页数：7

共 22 条

[1] Polymer-Fullerene Bulk-Heterojunction Solar Cells
Brabec, Christoph J.
Gowrisanker, Srinivas
Halls, Jonathan J. M.
Laird, Darin
Jia, Shijun
Williams, Shawn P.
[J]. ADVANCED MATERIALS, 2010, 22 (34) : 3839 - 3856
[2] Dou LT, 2012, NAT PHOTONICS, V6, P180, DOI [10.1038/nphoton.2011.356, 10.1038/NPHOTON.2011.356]
[3] Ultrafast Exciton Dissociation Followed by Nongeminate Charge Recombination in PCDTBT:PCBM Photovoltaic Blends
Etzold, Fabian
Howard, Ian A.
Mauer, Ralf
Meister, Michael
Kim, Tae-Dong
Lee, Kwang-Sup
Baek, Nam Seob
Laquai, Frederic
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (24) : 9469 - 9479
[4] Enhancing Field-Effect Mobility of Conjugated Polymers Through Rational Design of Branched Side Chains
Fu, Boyi
Baltazar, Jose
Sankar, Ashwin Ravi
Chu, Ping-Hsun
Zhang, Siyuan
Collard, David M.
Reichmanis, Elsa
[J]. ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (24) : 3734 - 3744
[5] Influence of the Position of the Side Chain on Crystallization and Solar Cell Performance of DPP-Based Small Molecules
Gevaerts, Veronique S.
Herzig, Eva M.
Kirkus, Mindaugas
Hendriks, Koen H.
Wienk, Martijn M.
Perlich, Jan
Mueller-Buschbaurn, Peter
Janssen, Rene A. J.
[J]. CHEMISTRY OF MATERIALS, 2014, 26 (02) : 916 - 926
[6] Importance of the Donor:Fullerene Intermolecular Arrangement for High-Efficiency Organic Photovoltaics
Graham, Kenneth R.
Cabanetos, Clement
Jahnke, Justin P.
Idso, Matthew N.
El Labban, Abdulrahman
Ndjawa, Guy O. Ngongang
Heumueller, Thomas
Vandewal, Koen
Salleo, Alberto
Chmelka, Bradley F.
Amassian, Aram
Beaujuge, Pierre M.
McGehee, Michael D.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (27) : 9608 - 9618
[7] He ZC, 2012, NAT PHOTONICS, V6, P591, DOI [10.1038/NPHOTON.2012.190, 10.1038/nphoton.2012.190]
[8] Semi-crystalline random conjugated copolymers with panchromatic absorption for highly efficient polymer solar cells
Jung, Jae Woong
Liu, Feng
Russell, Thomas P.
Jo, Won Ho
[J]. ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (11) : 3301 - 3307
[9] A high mobility conjugated polymer based on dithienothiophene and diketopyrrolopyrrole for organic photovoltaics
Jung, Jae Woong
Liu, Feng
Russell, Thomas P.
Jo, Won Ho
[J]. ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (05) : 6857 - 6861
[10] Record High Hole Mobility in Polymer Semiconductors via Side-Chain Engineering
Kang, Il
Yun, Hui-Jun
Chung, Dae Sung
Kwon, Soon-Ki
Kim, Yun-Hi
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (40) : 14896 - 14899

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