Ionic liquids with perfluorinated alkoxyaluminates

被引：22

作者：

Timofte, Tudor ^{[1
]}

Pitula, Slawomir ^{[1
]}

Mudring, Anja-Verena ^{[1
]}

机构：

[1] Ruhr Univ Bochum, D-44801 Bochum, Germany

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 26期

关键词：

WEAKLY COORDINATING ANIONS; RARE-EARTH IODIDES; COMPLEX-COMPOUNDS; SALTS; AL(ORF)(4)(-); CATION;

D O I：

10.1021/ic7009995

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ionic liquids with the weakly coordinating perfluoroalkoxyaluminate anions, Al(ORF)(4)(-), are obtained by a metathesis reaction of LiAI(ORF)(4) and [bmim]Cl or [bmpyr]Cl in high yields. The compounds [bmim][Al(hfip)(4)] and [bmpyr][Al(hfip)(4)] have surprisingly low viscosities at elevated temperatures (60 degrees C) and an exceptionally high electrochemical window, which might render them useful for certain applications.

引用

页码：10938 / 10940

页数：3

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