Metal hydrogen sulfates catalyzed meth oxymethylation of alcohols under solvent-free conditions

被引：25
|
作者：
Niknam, Khodabakhsh [1 ]
Zolfigol, Mohammad Ali
Shayegh, Mohsen
Zare, Reza
机构：
[1] Persian Gulf Univ, Fac Sci, Dept Chem, Bushehr 75169, Iran
[2] Bu Ali Sina Univ, Fac Chem, Hamadan 65174, Iran
来源：
JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 2007年 / 54卷 / 04期
关键词：
metal hydrogen sulfates; M(HSO4)(n); methoxymethylation; alcohols; formaldehyde dimethoxy acetal; solvent-free conditions;
D O I：
10.1002/jccs.200700153
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Methoxymethylation of a variety of alcohols was performed by using formaldehyde dimethoxy acetal in the presence of metal hydrogen sulfate M(HSO4)(n) at room temperature and solvent-free conditions. The methoxymethyl ethers (MOM-ethers) were obtained with high yields and purity.
引用
收藏
页码：1067 / 1073
页数：7
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