New types of heat-resistant, flame-retardant ferrocene-based polyamides with improved solubility

被引：24

作者：

Mehdipour-Ataei, Shahram ^{[1
]}

Babanzadeh, Samal ^{[1
]}

机构：

[1] Iran Polymer & Petrochem Inst, Tehran, Iran

来源：

REACTIVE & FUNCTIONAL POLYMERS | 2007年 / 67卷 / 10期

关键词：

polyamide; ferrocene; diamine; heat-resistant; flame-retardant;

D O I：

10.1016/j.reactfunctpolym.2007.05.012

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A novel ferrocenyl diamine (FDA) was prepared by the condensation reaction of 1, 1'-ferrocenedicarbonyl chloride with 2 mol of 2,6-bis(4-aminophenoxy)pyridine. A series of ferrocene-based polyamides was prepared via polycondensation reaction of FDA with various diacid chlorides in N-methyl-2-pyrrolidone (NMP) using trimethylchlorosilane (TMSCI) as activating agent. The monomer and polyamides were characterized and inherent viscosity, solubility, thermal stability and behavior, flame-retardancy, and crystallinity of the polymers were studied. The polymers showed good heat-resistant, flame-retardancy, and also improved solubility in polar aprotic solvents. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：883 / 892

页数：10

共 41 条

[1]

Abd-El-Aziz AS, 2002, MACROMOL RAPID COMM, V23, P743, DOI 10.1002/1521-3927(20020901)23:13<743::AID-MARC743>3.0.CO

[2]

2-K

[3] ARYLIDENE POLYMERS .18. SYNTHESIS AND THERMAL-BEHAVIOR OF ORGANOMETALLIC ARYLIDENE POLYESTERS CONTAINING FERROCENE DERIVATIVES IN THE MAIN CHAIN [J].