Sorption of cesium ions from aqueous solutions by multi-walled carbon nanotubes functionalized with copper ferrocyanide

被引:16
作者
Lee, Hyun-Kyu [1 ]
Choi, Jung Weon [1 ]
Oh, Wonzin [2 ]
Choi, Sang-June [1 ,2 ]
机构
[1] Kyungpook Natl Univ, Sch Architectural Civil Environm & Energy Engn, 80 Daehak Ro, Taegu 702701, South Korea
[2] Kyungpook Natl Univ, Res Inst Adv Energy Technol, 80 Daehak Ro, Taegu 702701, South Korea
基金
新加坡国家研究基金会;
关键词
Cesium; Multi-walled carbon nanotubes; Copper ferrocyanide; Sorption; SELECTIVE REMOVAL; EXCHANGE PROPERTIES; ADSORPTION; HEXACYANOFERRATE; WATER; AMINO; CADMIUM;
D O I
10.1007/s10967-015-4642-z
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this study, copper ferrocyanide-functionalized, multi-walled carbon nanotubes (MWCNT-CuFCs) were synthesized. The MWCNT-CuFCs exhibited a high capacity for sorbing Cs+ from aqueous solutions because of their strong affinity for Cs+ and high specific surface area. The sorption capacity of the MWCNT-CuFCs for Cs+ was dependent upon the initial pH of the solution. The sorption ability of the MWCNT-CuFCs for Cs+ was maintained even in the presence of co-existing ions (K+ and Na+). To determine the degree of Cs+ desorption from the MWCNT-CuFCs, a column-based desorption experiment was performed.
引用
收藏
页码:477 / 484
页数:8
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