Palladium(II) 2-mercaptobenzamide (o-SC6H4CONH2) complexes: Crystal structure of trans-[Pd(o-SC6H4CONH2)2(PPh3)2]

被引：3

作者：

Al-Jibori, Subhi A. ^{[1
]}

Al-Jibori, Ghassan H. H. ^{[1
]}

Saleh, Syran S. ^{[2
]}

Al-Janabi, Ahmed S. M. ^{[1
]}

Laguna, Mariano ^{[3
]}

Wagner, Christoph ^{[4
]}

机构：

[1] Tikrit Univ, Coll Sci, Dept Chem, Tikrit, Iraq

[2] Univ Kirkuk, Coll Sci, Dept Chem, Kirkuk, Iraq

[3] Univ Zaragoza, Fac Ciencias, Inst Sintesis Quim & Catalisis Homogenea ISQCH, Plaza S Francisco S-N, Zaragoza 50009, Spain

[4] Martin Luther Univ Halle Wittenberg, Inst Chem, Kurt Mothes Str 2, D-06120 Halle, Germany

来源：

POLYHEDRON | 2022年 / 216卷

关键词：

2-Mercaptobenzamide; Benzisothiazolinone; Mercury; Palladium; PLATINUM(II) SACCHARINATE COMPLEXES; MERCURY(II) SACCHARINATE; CO; FLUORESCENT; BIT;

D O I：

10.1016/j.poly.2022.115721

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Hg(mbm)(2)] (mbm = o-SC6H4CONH2) with Na2S releases Na[mbm] which reacts with Pd(II) salts to give [Pd(mbm)(2)]. While its precise molecular structure is unknown, [Pd(mbm)(2)] reacts with two equivalents of PPh3 to afford trans-[Pd(kappa(1)-mbm)(2)(PPh3)(2)] in which the mbm ligands bind through a sulfur atom. With dppf, a similar complex, [Pd(kappa(1)-mbm)(2)(kappa(2)-dppf)], is formulated with the mbm ligands being forced into a relative cis orientation. With dppm, a mixture of mononuclear [Pd(kappa(1)-mbm)(2)(dppm)] and binuclear [Pd(kappa(1)-mbm)(2)(mu-dppm)](2) results. The new complexes have been characterized by IR, H-1 and P-31{H-1} NMR, molar conductivity and elemental analysis, and in addition, the molecular structure of trans-[Pd(kappa(2)-mbm)(2)(PPh3)(2)] was confirmed by X-ray diffraction.

引用

页数：7

共 50 条

[41] Double Complex Salt [Pd(NH3)4][VO(H2O)(C2O4)2]·2H2O: Structure and Thermal Properties
Z. V. Rudzis
S. N. Vorobyeva
T. S. Sukhikh
E. Y. Filatov
V. A. Nadolinny
S. N. Berdyugin
S. V. Korenev
Journal of Structural Chemistry, 2025, 66 (5) : 955 - 965
[42] Experimental study of the [ZnCl2(THF)2] catalyzed cis/trans-isomerization of [Pd(C6Cl2F3)Me(PPh3)2] and of the transmetalation of trans-[PdCl (C6Cl2F3)(PPh3)2] with [ZnMeCl(THF)2]
Carrasco, Desire
Casares, Juan A.
INORGANICA CHIMICA ACTA, 2021, 517
[43] New aryl phosphinite ligands avoiding ortho-metallation:: Synthesis and molecular structures of trans-[PdCl2(PPh2OR)2] and trans-[Rh(CO)Cl(PPh2OR)2] (R=2,4,6-Me3C6H2; 2,6-Ph2C6H3)
Chahen, L
Karmazin-Brelot, L
Süss-Fink, G
INORGANICA CHIMICA ACTA, 2005, 358 (12) : 3417 - 3422
[44] Vibrational spectra of Cs2Cu(SO4)2•6H2O and Cs2Cu(SeO4)2•nH2O (n=4, 6) with a crystal structure determination of the Tutton salt CS2CU(SeO4)2•6H2O
Wildner, M.
Marinova, D.
Stoilova, D.
JOURNAL OF MOLECULAR STRUCTURE, 2016, 1106 : 440 - 451
[45] CRYSTAL STRUCTURES OF Ln（o-ClC6H4CO2）3（H2O）[Ln = Tb（Ⅲ） , Nd（Ⅲ）]
Ma Jian-Fang Jin Zhong-Sheng Ni Jia-Zuan Changchun Institute of Applied Chemistry
结构化学, 1991, (02) : 121 - 124
[46] Dinuclear cyclometallated complexes of Pd-II with diphosphines. X-ray crystal structure of [1,4-{Pd[2,4-(MeO)(2)C6H2C(H)=N]}(2)-C6H4{Ph(2)P(CH2)(3)PPh(2)-P,P}(2)][PF6](2)
Vila, JM
Gayoso, M
Torres, ML
Fernandez, JJ
Fernandez, A
Ortigueira, JM
Bailey, NA
Adams, H
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 511 (1-2) : 129 - 138
[47] Cyclometallation of 2-phenylaniline and (R)-alpha-methylbenylamine by palladium(II) acetate. X-ray molecular structure of [Pd{2-(2'-NH2C6H4)C6H4}Br(PPh(3))]
Albert, J
Granell, J
Luque, A
Minguez, J
Moragas, R
FontBardia, M
Solans, X
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 522 (01) : 87 - 95
[48] Sulfur-assisted chloride and triphenylphosphine dissociation of palladium(II) complex [Pd(PPh3)2(η1-SCNMe2)(Cl)].: X-ray structures of [Pd(PPh3)2(η1-SCNMe2)(Cl)], [Pd(PPh3)(Cl)]2 (μ, η2-SCNMe2)2, and [Pd(PPh3)2(η2-SCNMe2)][PF6]
Yih, KH
Lee, GH
Wang, Y
INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (05) : 577 - 580
[49] Synthesis and characterization of isomanolonitrile dithiolato palladium complexes. Crystal structure of (PPh3)(2)Pd(S2C4N2) and (Et4N)(2)WS4Pd(S2C4N2)
Long, DL
Zheng, H
Xin, XQ
Sakane, G
Shibahara, T
POLYHEDRON, 1997, 16 (24) : 4305 - 4311
[50] SYNTHESIS AND CRYSTAL STRUCTURE OF DINUCLEAR IRON CARBONYL DERIVATIVE （μ-SC6H5） (μ-P （SC6H5）2) Fe2 （CO）5 (P-（SC6H5）3)
Wu Bin-Fang Su Han-Quan Yan Xiu-Ying Hu Xing Liu Qi-WangFuzhou Laboratory of Structural Chemistry
结构化学, 1992, (05) : 339 - 342

← 1 2 3 4 5 →