Palladium(II) 2-mercaptobenzamide (o-SC6H4CONH2) complexes: Crystal structure of trans-[Pd(o-SC6H4CONH2)2(PPh3)2]

被引：3

作者：

Al-Jibori, Subhi A. ^{[1
]}

Al-Jibori, Ghassan H. H. ^{[1
]}

Saleh, Syran S. ^{[2
]}

Al-Janabi, Ahmed S. M. ^{[1
]}

Laguna, Mariano ^{[3
]}

Wagner, Christoph ^{[4
]}

机构：

[1] Tikrit Univ, Coll Sci, Dept Chem, Tikrit, Iraq

[2] Univ Kirkuk, Coll Sci, Dept Chem, Kirkuk, Iraq

[3] Univ Zaragoza, Fac Ciencias, Inst Sintesis Quim & Catalisis Homogenea ISQCH, Plaza S Francisco S-N, Zaragoza 50009, Spain

[4] Martin Luther Univ Halle Wittenberg, Inst Chem, Kurt Mothes Str 2, D-06120 Halle, Germany

来源：

POLYHEDRON | 2022年 / 216卷

关键词：

2-Mercaptobenzamide; Benzisothiazolinone; Mercury; Palladium; PLATINUM(II) SACCHARINATE COMPLEXES; MERCURY(II) SACCHARINATE; CO; FLUORESCENT; BIT;

D O I：

10.1016/j.poly.2022.115721

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Hg(mbm)(2)] (mbm = o-SC6H4CONH2) with Na2S releases Na[mbm] which reacts with Pd(II) salts to give [Pd(mbm)(2)]. While its precise molecular structure is unknown, [Pd(mbm)(2)] reacts with two equivalents of PPh3 to afford trans-[Pd(kappa(1)-mbm)(2)(PPh3)(2)] in which the mbm ligands bind through a sulfur atom. With dppf, a similar complex, [Pd(kappa(1)-mbm)(2)(kappa(2)-dppf)], is formulated with the mbm ligands being forced into a relative cis orientation. With dppm, a mixture of mononuclear [Pd(kappa(1)-mbm)(2)(dppm)] and binuclear [Pd(kappa(1)-mbm)(2)(mu-dppm)](2) results. The new complexes have been characterized by IR, H-1 and P-31{H-1} NMR, molar conductivity and elemental analysis, and in addition, the molecular structure of trans-[Pd(kappa(2)-mbm)(2)(PPh3)(2)] was confirmed by X-ray diffraction.

引用

页数：7

共 50 条

[21] New crystal modification of the di(nitrato)di(aqua)palladium(II) complex β-trans-[Pd(NO3)2(H2O)2]
S. A. Gromilov
S. P. Khranenko
I. A. Baidina
A. V. Virovets
E. V. Peresypkina
Journal of Structural Chemistry, 2008, 49 : 160 - 164
[22] New crystal modification of the di(nitrato)di(aqua)palladium(II) complex β-trans-[Pd(NO3)2(H2O)2]
Gromilov, S. A.
Khranenko, S. P.
Baidina, I. A.
Virovets, A. V.
Peresypkina, E. V.
JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 49 (01) : 160 - 164
[23] Synthesis and crystal structures of the complexes trans-[CoIII(py)4F2][H2F3] and [Pd(py)4]F2 • 1.5 HF • 2 H2O
Holzbock, J
Sawodny, W
Thewalt, U
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2000, 626 (12): : 2563 - 2568
[24] CRYSTAL STRUCTURE OF [Tm4（p-NO2C6H4CO2）12（H2O）10·2H2O
Ma Jian-Fang Jin Zhong-Sheng Ni Jia-Zuan Changchun Institute of Applied Chemistry
结构化学, 1991, (01) : 56 - 59
[25] Palladium acetate complexes with morpholine and 4-methylmorpholine. The structure of Pd(C4H9ON)2(OAc)2 · 2H2O
O. N. Shishilov
T. A. Stromnova
A. V. Churakov
L. G. Kuz’mina
I. A. Efimenko
Russian Journal of Inorganic Chemistry, 2006, 51 : 574 - 580
[26] Photo-assisted formation of a chelating diphos ligand from PPh3 and a cyclometallated [P(C6H4)(C6H5)2]- ligand.: Crystal structure of Pd{η2-o-[P(C6H5)2]2(C6H4)}Br2
Estevan, F
García-Bernabé, A
Lahuerta, P
Sanaú, M
Ubeda, MA
Galán-Mascarós, JR
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 596 (1-2) : 248 - 251
[27] Crystal structure of K2[Pd(NO2)4]•2H2O
Gromilov, S. A.
Khranenko, S. P.
Baidina, I. A.
Kuratieva, N. V.
JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 49 (01) : 165 - 169
[28] CRYSTAL STRUCTURES OF Ln（o-HOC6H4CO2）3 （H2O）2·2H2O [Ln =Tb,Ho]
Ma Jian-Fang Jin Zhong-Sheng Ni Jia-Zuan Changchun Institute of Applied Chemistry
结构化学, 1991, (02) : 125 - 128
[29] Crystal structure of K2[Pd(NO2)4]·2H2O
S. A. Gromilov
S. P. Khranenko
I. A. Baidina
N. V. Kuratieva
Journal of Structural Chemistry, 2008, 49 : 165 - 169
[30] Reactions of [Rh(Tp*)(PPh3)2] (Tp* = hydrotris(3,5-dimethylpyrazolyl)-borate) involving fragmentation or loss of Tp*.: Structures of [Rh(Cl)2(H)(PPh3)2(pz*)], [(PPh3)2Rh(μ-SC6F5)2Rh (SC6F5)(H)(PPh3)(pz*)] (pz*=3,5-dimethylpyrazole) and [{Rh(Cl)2(PPh3)2}2Hg]
Circu, V
Fernandes, MA
Carlton, L
POLYHEDRON, 2003, 22 (25-26) : 3293 - 3298

← 1 2 3 4 5 →