Quint points lattice in a driven Belousov-Zhabotinsky reaction model

被引:25
|
作者
Field, Richard J. [1 ]
Freire, Joana G. [2 ,3 ]
Gallas, Jason A. C. [3 ,4 ]
机构
[1] Univ Montana, Dept Chem, Missoula, MT 59812 USA
[2] Univ Lisbon, Inst Dom Luiz, P-1749016 Lisbon, Portugal
[3] Inst Altos Estudos Paraiba, BR-58039190 Joao Pessoa, Paraiba, Brazil
[4] Complex Sci Ctr, 9225 Collins Ave,Suite 1208, Surfside, FL 33154 USA
关键词
CHEMICAL-SYSTEMS; CHAOS; OSCILLATIONS; PERIODICITY;
D O I
10.1063/5.0047167
中图分类号
O29 [应用数学];
学科分类号
070104 ;
摘要
We report the discovery of a regular lattice of exceptional quint points in a periodically driven oscillator, namely, in the frequency-amplitude control parameter space of a photochemically periodically perturbed ruthenium-catalyzed Belousov-Zhabotinsky reaction model. Quint points are singular boundary points where five distinct stable oscillatory phases coalesce. While spikes of the activator show a smooth and continuous variation, the spikes of the inhibitor show an intricate but regular branching into a myriad of stable phases that have fivefold contact points. Such boundary points form a wide parameter lattice as a function of the frequency and amplitude of light absorption. These findings revise current knowledge about the topology of the control parameter space of a celebrated prototypical example of an oscillating chemical reaction.
引用
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页数:6
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