Suppression of Schlenk Equilibration and Heavier Alkaline Earth Alkyl Catalysis: A Dearomatization Strategy

被引：46
作者：
Arrowsmitla, Merle [1 ]
Hill, Michael S. [1 ]
Kociok-Koehn, Gabriele [1 ]
机构：
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
来源：
ORGANOMETALLICS | 2011年 / 30卷 / 06期
基金：
英国工程与自然科学研究理事会;
关键词：
BIDENTATE NITROGEN LIGANDS; RAY CRYSTAL-STRUCTURE; INTRAMOLECULAR HYDROAMINATION; COMPLEXES; CALCIUM; MAGNESIUM; BARIUM; SEMIHYDROGENATION; AMINOALKENES; TERPYRIDINE;
D O I：
10.1021/om200028m
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of a bis(imino)acenapthene with the heavier alkaline earth dialkyls [Ae{CH(SiMe3)(2)}(2)(THF)(2)] (Ac = Mg, Ca, Sr) results in deromatization of the aromatic ligand and the isolation of heteroleptic alkyl species which show unprecedented stability toward Schlenk-type redistribution and exceptional catalytic activity toward the hydroamination of aminoalkeries.
引用
收藏
页码：1291 / 1294
页数：4
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