Use of pyridinium and pyrrolidinium ionic liquids for removal of toluene from gas streams

被引：8

作者：

Cichowska-Kopczynska, Iwona ^{[1
]}

Aranowski, Robert ^{[1
]}

机构：

[1] Gdansk Univ Technol, Dept Proc Engn & Chem Technol, Ul Narutowicza 11-12, Gdansk, Poland

来源：

JOURNAL OF MOLECULAR LIQUIDS | 2020年 / 298卷

关键词：

Ionic liquid; Supported ionic liquid membrane; Toluene; Separation; Selectivity; VOC; AROMATIC-HYDROCARBONS; VAPOR PERMEATION; THERMOPHYSICAL PROPERTIES; VOCS/N-2; MIXTURES; MUTUAL SOLUBILITY; ORGANIC-COMPOUNDS; SEPARATION; EXTRACTION; MEMBRANES; IMIDAZOLIUM;

D O I：

10.1016/j.molliq.2019.112091

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Separation of toluene from a toluene/N-2 gas mixture using supported liquid membranes based on a series of pyridinium (1-butylpyridinium- bis(trifluoromethylsulfonyl)imide - [C4Py][Tf2N], 1-hexylpyridinium trifluoromethanesulfone [C6Py][Tf2N]) and pyrrolidinium (1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl)imide - [C(4)Pyrr][Tf2N], 1-hexyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl) imide - [C(6)Pyrr][Tf2N], 1-butyl-1-methylpyrrolidinium trifluoromethanesulfone - [C(4)Pyrr][TfO]) ionic liquids (ILs) was studied over a wide range of temperatures. The toluene permeability and selectivity of separation was investigated in terms of cation and anion type. It was found that both pyridinium and pyrrolidinium ILs show high toluene permeability, up to 2034 barrers, with satisfying separation selectivity. An analysis of two key factors that have an influence on this process, that is diffusion in a form of resistance resulting from the viscosity of membrane liquid and the solubility expressed by the partition coefficient, was made. (C) 2019 Elsevier B.V. All rights reserved.

引用

页数：9

共 61 条

[1] On Big Lattices of Classes of R-modules Defined by Closure Properties
Alvarado Garcia, Alejandro
Rincon Mejia, Hugo Alberto
Rios Montes, Jose
[J]. ADVANCES IN RING THEORY, 2010, : 19 - +
[2] Anderson J., 2007, ACCOUNTS CHEM RES, P1208
[3] Thermophysical Properties of Pure Ionic Liquids: Review of Present Situation
Aparicio, Santiago
Atilhan, Mert
Karadas, Ferdi
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2010, 49 (20) : 9580 - 9595
[4] Bis{(trifluoromethyl)sulfonyl}amide ionic liquids as solvents for the extraction of aromatic hydrocarbons from their mixtures with alkanes: effect of the nature of the cation
Arce, Alberto
Earle, Martyn J.
Rodriguez, Hector
Seddon, Kenneth R.
Soto, Ana
[J]. GREEN CHEMISTRY, 2009, 11 (03) : 365 - 372
[5] Optimized Ionic Liquids for Toluene Absorption
Bedia, Jorge
Ruiz, Elia
de Riva, Juan
Ferro, Victor R.
Palomar, Jose
Jose Rodriguez, Juan
[J]. AICHE JOURNAL, 2013, 59 (05) : 1648 - 1656
[6] Billmeyer F. W., 1984, TXB POLYM SCI
[7] Physical properties of pyridinium ionic liquids
Bittner, Bozena
Wrobel, Rafal J.
Milchert, Eugeniusz
[J]. JOURNAL OF CHEMICAL THERMODYNAMICS, 2012, 55 : 159 - 165
[8] Gas solubilities in room temperature ionic liquids - Correlation between RTiL-molar mass and Henry's law constant
Blath, Jessica
Christ, Michael
Deubler, Natalie
Hirth, Thomas
Schiestel, Thomas
[J]. CHEMICAL ENGINEERING JOURNAL, 2011, 172 (01) : 167 - 176
[9] Branco LC, 2002, ANGEW CHEM INT EDIT, V41, P2771, DOI 10.1002/1521-3773(20020802)41:15<2771::AID-ANIE2771>3.0.CO
[10] 2-U

← 1 2 3 4 5 6 7 →