Development of thermoplastic polyurethane/polyaniline-doped membranes for the separation of glycine through electrodialysis

被引:1
作者
Khurram [1 ]
Qaiser, Asif Ali [2 ]
Saleem, Rashid [3 ]
Ali, Naveed Shahzad [1 ]
Nazir, Shahbaz [4 ]
Hussain, Tousif [5 ]
Ghaffar, Abdul [1 ]
机构
[1] Univ Engn & Technol, Dept Chem, Lahore, Pakistan
[2] Univ Engn & Technol Lahore, Dept Polymer & Proc Engn, Lahore, Pakistan
[3] Govt Coll Univ, Dept Chem, Katchery Rd, Lahore, Pakistan
[4] Univ Punjab, Dept Chem, Lahore, Pakistan
[5] Govt Coll Univ, Dept Ctr Adv Studies Phys, Lahore, Pakistan
关键词
Thermoplastic polyurethane; sulfonic acid dopants; electrodialysis; polyaniline; glycine; ANION-EXCHANGE MEMBRANE; AMINO-ACIDS; ELECTRICAL-CONDUCTIVITY; THERMAL-DEGRADATION; POLYANILINE; BLENDS; COMPOSITES; RECOVERY;
D O I
10.3906/kim-1907-2
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Recently, membrane-based separation processes, particularly electrodialysis, have attracted attention for the separation and purification of organic and amino acids from animal feedstock waste. In this study, cation exchange membranes were synthesized by making a composite of thermoplastic polyurethane and polyaniline (PANI) via the doping of various aromatic sulfonic acids, such as beta-naphthol sulfonic acid and phenol sulfonic acid. The PANI was prepared using a standard method, which was further used in the composite blending at varying concentrations of 10%-20%. The impact of the concentration of PANI and the nature of the dopant on the membrane characteristics were comparatively studied. The membranes were analyzed by electric conductivity, water swelling, morphological studies (SEM), and thermogravimetric analysis. The membranes were used for the separation of glycine hydrochloride via electrodialysis.
引用
收藏
页码:224 / 236
页数:13
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