A reactive blend of electroactive polymers exhibiting synergistic effects on self-healing and anticorrosion properties

被引：14
作者：
Chuo, Tsai-Wei [1 ]
Yeh, Jui-Ming [2 ,3 ]
Liu, Ying-Ling [1 ]
机构：
[1] Natl Tsing Hua Univ, Dept Chem Engn, Hsinchu 30013, Taiwan
[2] Chung Yuan Christian Univ, Dept Chem, Taoyuan 32023, Taiwan
[3] Chung Yuan Christian Univ, Ctr Nanotechnol, Taoyuan 32023, Taiwan
来源：
RSC ADVANCES | 2016年 / 6卷 / 60期
关键词：
COATINGS; EPOXY; MICROCAPSULES; CYCLODEXTRIN; PERFORMANCE; SURFACE; RESIN; OIL;
D O I：
10.1039/c6ra09643c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reactive blends of polymers provide a convenient and effective approach to prepare functional materials exhibiting integrated or synergistic properties. In this work we report the first electrically-induced self-healing anticorrosion material composed of (a) an electrically-responsive crosslinked polymer of ferrocene modified poly(glycidylmethacrylate) and a difunctional beta-cyclodextrin compound and (b) an electroactive polymer of aniline trimer. The two components exhibit synergistic effects on both self-healing and anticorrosion properties. A 94% of protection efficiency for anticorrosion and a 92.5% self-healing recovery of anticorrosion protection efficiency have been recorded.
引用
收藏
页码：55593 / 55598
页数：6
相关论文
共 36 条
  • [1] Self-healing anticorrosion coatings based on pH-sensitive polyelectrolyte/inhibitor sandwichlike nanostructures
    Andreeva, Daria V.
    Fix, Dmitri
    Moehwald, Helmuth
    Shchukin, Dmitry G.
    [J]. ADVANCED MATERIALS, 2008, 20 (14) : 2789 - +
  • [2] [Anonymous], 2014, Journal of Chemistry, DOI DOI 10.1155/2014/848571
  • [3] Exploring the interfaces between metal electrodes and aqueous electrolytes with electrochemical impedance spectroscopy
    Bandarenka, Aliaksandr S.
    [J]. ANALYST, 2013, 138 (19) : 5540 - 5554
  • [4] Nanocontainer-Based Anticorrosive Coatings: Effect of the Container Size on the Self-Healing Performance
    Borisova, Dimitriya
    Akcakayiran, Dilek
    Schenderlein, Matthias
    Moehwald, Helmuth
    Shchukin, Dmitry G.
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2013, 23 (30) : 3799 - 3812
  • [5] Ferrocene-β-Cyclodextrin Conjugates: Synthesis, Supramolecular Behavior, and Use as Electrochemical Sensors
    Casas-Solvas, Juan M.
    Ortiz-Salmeron, Emilia
    Fernandez, Ignacio
    Garcia-Fuentes, Luis
    Santoyo-Gonzalez, Francisco
    Vargas-Berenguel, Antonio
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (33) : 8146 - 8162
  • [6] Polyurethane Prepared from Neem Oil Polyesteramides for Self-Healing Anticorrosive Coatings
    Chaudhari, Ashok B.
    Tatiya, Pyus D.
    Hedaoo, Rahul K.
    Kulkarni, Ravindra D.
    Gite, Vikas V.
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2013, 52 (30) : 10189 - 10197
  • [7] Electrically driven self-healing polymers based on reversible guest-host complexation of -cyclodextrin and ferrocene
    Chuo, Tsai-Wei
    Wei, Ta-Chin
    Liu, Ying-Ling
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2013, 51 (16) : 3395 - 3403
  • [8] Self-healing anticorrosive organic coating based on an encapsulated water reactive silyl ester: Synthesis and proof of concept
    Garcia, S. J.
    Fischer, H. R.
    White, P. A.
    Mardel, J.
    Gonzalez-Garcia, Y.
    Mol, J. M. C.
    Hughes, A. E.
    [J]. PROGRESS IN ORGANIC COATINGS, 2011, 70 (2-3) : 142 - 149
  • [9] A combined redox-competition and negative-feedback SECM study of self-healing anticorrosive coatings
    Gonzalez-Garcia, Y.
    Garcia, S. J.
    Hughes, A. E.
    Mol, J. M. C.
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2011, 13 (10) : 1094 - 1097
  • [10] Polyelectrolyte complexes as a "smart'' depot for self-healing anticorrosion coatings
    Grigoriev, Dmitry O.
    Koehler, Karen
    Skorb, Ekaterina
    Shchukin, Dmitry G.
    Moehwald, Helmuth
    [J]. SOFT MATTER, 2009, 5 (07) : 1426 - 1432
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