EPR evidence of tetrahalogeno(triphenylmethylimido)rhenium(VI) complexes [Re{NC(C6H5)3}X4] (X = Cl, Br)

被引：9
作者：
Voigt, A
Abram, U
Kirmse, R
机构：
[1] Univ Leipzig, Inst Inorgan Chem, D-04103 Leipzig, Germany
[2] Dresden Univ Technol, Inst Analyt Chem, Inst Radiochem, Forschungszentrum Rossendorf, D-10162 Dresden, Germany
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 1998年 / 1卷 / 06期
关键词：
rhenium complexes; imido complexes; EPR study;
D O I：
10.1016/S1387-7003(98)00054-9
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The EPR detection of the formation of two tetrahologeno Re-VI (5d(1)) complexes containing a nitrogen bridge 'Re-N-E' (E=C+(C6H5)(3)) is described. Their EPR parameters are compared to those of the [ReNX4](-) (X = Cl, Br) parent complexes; spin-density changes are discussed. (C) 1998 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：203 / 205
页数：3
相关论文
共 9 条
1