Ruthenium complex catalyzed hydrosilylation of esters: a facile transformation of esters to alkyl silyl acetals and aldehydes

被引：65

作者：

Igarashi, M ^{[1
]}

Mizuno, R ^{[1
]}

Fuchikami, T ^{[1
]}

机构：

[1] Sagami Chem Res Ctr, Kanagawa 2290012, Japan

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 11期

关键词：

ruthenium and compounds; catalysts; silicon and compounds; esters; acetals; aldehydes;

D O I：

10.1016/S0040-4039(01)00094-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydrosilylation of esters takes place in the presence of ruthenium catalysts to afford the corresponding alkyl silyl acetals in moderate to good yields, which can be converted into aldehydes by hydrolysis. (C) 2001 Elsevier Science Ltd. All rights reserved.

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收藏

页码：2149 / 2151

页数：3

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