Accurate labeling of the light-actinide O4,5 edges

被引：21

作者：

Moore, Kevin T. ^{[1
]}

van der Laan, Gerrit

机构：

[1] Lawrence Livermore Natl Lab, Chem & Mat Sci Directorate, Livermore, CA 94550 USA

[2] SERC, Daresbury Lab, Magnet Spectroscopy Grp, Warrington WA4 4AD, Cheshire, England

来源：

ULTRAMICROSCOPY | 2007年 / 107卷 / 12期

关键词：

EELS; TEM; actinide; absorption;

D O I：

10.1016/j.ultramic.2007.01.014

中图分类号：

TH742 [显微镜];

学科分类号：

摘要：

In this short article, the accurate labeling of the O-4,O-5 edges of the light actinides is addressed. The O-4 and O-5 edges are both contained in what is termed the 'giant resonance' and the smaller 'pre-peak' that is observed is a consequence of first-order perturbation by the 5d spin-orbit interaction on the 5d,5f exchange splitting. Thus, the small pre-peak in the actinide 5d --> 5f transition should not be labeled the OS peak, but rather the Delta S = 1 peak. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：1201 / 1206

页数：6

共 18 条

[1] X-RAY PHOTOEMISSION-STUDY OF PLUTONIUM METAL [J].

BAPTIST, R ;

COURTEIX, D ;

CHAYROUSE, J ;

HEINTZ, L .

JOURNAL OF PHYSICS F-METAL PHYSICS, 1982, 12 (09) :2103-2114

[2] THEORETICAL CALCULATION OF ATOMIC SPECTRA USING DIGITAL COMPUTERS [J].

COWAN, RD .

JOURNAL OF THE OPTICAL SOCIETY OF AMERICA, 1968, 58 (06) :808-&

[3] RAISING OF DISCRETE LEVELS INTO FAR CONTINUUM [J].

DEHMER, JL ;

STARACE, AF ;

FANO, U ;

SUGAR, J ;

COOPER, JW .

PHYSICAL REVIEW LETTERS, 1971, 26 (25) :1521-&

[4] CALCULATED PHOTOEMISSION SPECTRA OF THE 5F STATES IN THE ACTINIDES [J].

GERKEN, F ;

SCHMIDTMAY, J .

JOURNAL OF PHYSICS F-METAL PHYSICS, 1983, 13 (07) :1571-1580

[5] NEAR-EDGE X-RAY-ABSORPTION FINE-STRUCTURE IN URANIUM-COMPOUNDS [J].

KALKOWSKI, G ;

KAINDL, G ;

BREWER, WD ;

KRONE, W .

PHYSICAL REVIEW B, 1987, 35 (06) :2667-2677

[6] Oxidation and aging in U and Pu probed by spin-orbit sum rule analysis: Indications for covalent metal-oxide bonds [J].

Moore, KT ;

van der Laan, G ;

Haire, RG ;

Wall, MA ;

Schwartz, AJ .

PHYSICAL REVIEW B, 2006, 73 (03)

[7] Electron-energy-loss spectroscopy and X-ray absorption spectroscopy as complementary probes for complex f-electron metals:: cerium and plutonium [J].

Moore, KT ;

Wall, MA ;

Schwartz, AJ ;

Chung, BW ;

Morton, SA ;

Tobin, JG ;

Lazar, S ;

Tichelaar, FD ;

Zandbergen, HW ;

Söderlind, P ;

van der Laan, G .

PHILOSOPHICAL MAGAZINE, 2004, 84 (10) :1039-1056

[8] Failure of Russell-Saunders coupling in the 5f states of plutonium -: art. no. 196404 [J].

Moore, KT ;

Wall, MA ;

Schwartz, AJ ;

Chung, BW ;

Shuh, DK ;

Schulze, RK ;

Tobin, JG .

PHYSICAL REVIEW LETTERS, 2003, 90 (19) :4

[9] CALCULATION OF MAGNETIC-X-RAY DICHROISM IN 4D AND 5D ABSORPTION-SPECTRA OF ACTINIDES [J].

OGASAWARA, H ;

KOTANI, A ;

THOLE, BT .

PHYSICAL REVIEW B, 1991, 44 (05) :2169-2181

[10] Calculation of rare-earth 4d giant-absorption spectra with multiplet effects and decay processes [J].

Ogasawara, H ;

Kotani, A .

JOURNAL OF SYNCHROTRON RADIATION, 2001, 8 :220-222

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