Oxygen-vacancy-related high-temperature dielectric relaxation in SrTiO3 ceramics

被引:88
|
作者
Wang, Xiaofei [1 ]
Lu, Xiaomei [1 ]
Zhang, Chao [1 ]
Wu, Xiaobo [1 ]
Cai, Wei [1 ]
Peng, Song [1 ]
Bo, Huifeng [1 ]
Kan, Yi [1 ]
Huang, Fengzhen [1 ]
Zhu, Jinsong [1 ]
机构
[1] Nanjing Univ, Dept Phys, Natl Lab Solid State Microstruct, Nanjing 210093, Peoples R China
基金
美国国家科学基金会;
关键词
ceramics; crystal structure; dielectric losses; dielectric materials; dielectric relaxation; strontium compounds; vacancies (crystal); THIN-FILMS; 65; K; FERROELECTRICS; ANOMALIES; TITANATE; NONLINEARITY; ZRO2;
D O I
10.1063/1.3430987
中图分类号
O59 [应用物理学];
学科分类号
摘要
Quantum paraelectric SrTiO3 has resulted in many investigations because of the anomalous properties. Here, using the conventional solid-state reaction method, we fabricated polycrystalline SrTiO3 ceramics with pure cubic perovskite structure. A dielectric loss peak is observed at around 450 K and 100 Hz and it shifts to higher temperature with increasing frequency. The typical high-temperature dielectric relaxation process is confirmed to be related to the oxygen vacancies (OVs) inside ceramics. More interestingly, a Cole-Cole fitting to loss peaks reveals a weaker correlation among OVs for such dielectric materials compared with that of ferroelectrics. (C) 2010 American Institute of Physics. [doi: 10.1063/1.3430987]
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页数:4
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