Oxygen-vacancy-related high-temperature dielectric relaxation in SrTiO3 ceramics

被引:88
|
作者
Wang, Xiaofei [1 ]
Lu, Xiaomei [1 ]
Zhang, Chao [1 ]
Wu, Xiaobo [1 ]
Cai, Wei [1 ]
Peng, Song [1 ]
Bo, Huifeng [1 ]
Kan, Yi [1 ]
Huang, Fengzhen [1 ]
Zhu, Jinsong [1 ]
机构
[1] Nanjing Univ, Dept Phys, Natl Lab Solid State Microstruct, Nanjing 210093, Peoples R China
基金
美国国家科学基金会;
关键词
ceramics; crystal structure; dielectric losses; dielectric materials; dielectric relaxation; strontium compounds; vacancies (crystal); THIN-FILMS; 65; K; FERROELECTRICS; ANOMALIES; TITANATE; NONLINEARITY; ZRO2;
D O I
10.1063/1.3430987
中图分类号
O59 [应用物理学];
学科分类号
摘要
Quantum paraelectric SrTiO3 has resulted in many investigations because of the anomalous properties. Here, using the conventional solid-state reaction method, we fabricated polycrystalline SrTiO3 ceramics with pure cubic perovskite structure. A dielectric loss peak is observed at around 450 K and 100 Hz and it shifts to higher temperature with increasing frequency. The typical high-temperature dielectric relaxation process is confirmed to be related to the oxygen vacancies (OVs) inside ceramics. More interestingly, a Cole-Cole fitting to loss peaks reveals a weaker correlation among OVs for such dielectric materials compared with that of ferroelectrics. (C) 2010 American Institute of Physics. [doi: 10.1063/1.3430987]
引用
收藏
页数:4
相关论文
共 50 条
  • [31] Influence of A-site deficiency on oxygen-vacancy-related dielectric relaxation, electrical and temperature stability properties of CuO-doped NKN-based piezoelectric ceramics
    Tsai, Cheng-Che
    Chu, Sheng-Yuan
    Hong, Cheng-Shong
    Yang, Song-Ling
    CERAMICS INTERNATIONAL, 2013, 39 : S165 - S170
  • [32] OPERATION OF HIGH-TEMPERATURE RF SQUID MAGNETOMETERS USING DIELECTRIC SRTIO3 RESONATORS
    ZHANG, Y
    GOTTSCHLICH, M
    SOLTNER, H
    SODTKE, E
    SCHUBERT, J
    ZANDER, W
    BRAGINSKI, AI
    APPLIED PHYSICS LETTERS, 1995, 67 (21) : 3183 - 3185
  • [33] SrTiO3 doped KLBBNT ceramics with wide dielectric temperature stable range and high permittivity
    Qiao, Yulong
    Li, Jin
    Li, Weili
    Wang, Mengyang
    Ding, Hewei
    Li, Menglu
    Yang, Xiongbo
    Tan, Xinyu
    MATERIALS TODAY COMMUNICATIONS, 2024, 40
  • [34] High-temperature superconductivity at the FeSe/SrTiO3 interface
    Xiang, Yuan-Yuan
    Wang, Fa
    Wang, Da
    Wang, Qiang-Hua
    Lee, Dung-Hai
    PHYSICAL REVIEW B, 2012, 86 (13)
  • [35] Oxygen-vacancy-related dielectric relaxations in Na0.5K0.5NbO3
    Wang, C. C.
    Wang, J.
    Sun, X. H.
    Liu, L. N.
    Zhang, J.
    Zheng, J.
    Cheng, C.
    SOLID STATE COMMUNICATIONS, 2014, 179 : 29 - 33
  • [36] Dielectric properties of multilayered SrTiO3 thin films with graded oxygen vacancy concentration
    Liu, XZ
    Li, YR
    APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2006, 83 (01): : 67 - 72
  • [37] Dielectric properties of multilayered SrTiO3 thin films with graded oxygen vacancy concentration
    X.Z. Liu
    Y.R. Li
    Applied Physics A, 2006, 83 : 67 - 72
  • [38] Ab initio study of the oxygen vacancy in SrTiO3
    Astala, R
    Bristowe, PD
    MODELLING AND SIMULATION IN MATERIALS SCIENCE AND ENGINEERING, 2001, 9 (05) : 415 - 422
  • [39] PHOTOELECTROCHEMICAL EVALUATION OF OXYGEN VACANCY DIFFUSIVITIES IN SRTIO3
    GEALY, FD
    TULLER, HL
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (8B) : C472 - C472
  • [40] Study on the electronic structure of SrTiO3 with oxygen vacancy
    Yang, Chen-Xing
    Liu, Ting-Yu
    Cheng, Zhi-Jun
    Gan, Hai-Xiu
    Rengong Jingti Xuebao/Journal of Synthetic Crystals, 2012, 41 (01): : 232 - 237