Efficient electrode material of restacked Na-V2O5-graphene nanocomposite for Na-ion batteries

被引:12
作者
Park, Boyeon [1 ]
Oh, Seung Mi [1 ]
Jo, Yun Kyung [1 ]
Hwang, Seong-Ju [1 ]
机构
[1] Ewha Womans Univ, Coll Nat Sci, Dept Chem & Nanosci, Seoul 03760, South Korea
基金
新加坡国家研究基金会;
关键词
Nanosheets; Restacking; Nanocomposites; Reduced graphene oxide; Vanadium oxide; Na-ion batteries; REDUCED GRAPHENE OXIDE; VANADIUM; NANOSHEETS; COMPOSITE; NANOBELTS;
D O I
10.1016/j.matlet.2016.04.161
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Efficient electrode material of Na-V2O5-reduced graphene oxide (rG-O) nanocomposite is synthesized by the restacking of anionic component nanosheets with Na+ ions at room temperature. The restacked Na-V2O5-rG-O nanocomposite shows layer-by-layer-ordered structure of V2O5/rG-O nanosheets and Na+ ions with mesoporous stacking structure and expanded surface area. Upon the restacking with rG-O, the pentavalent V5+ oxidation state and layered lattice of vanadium oxide nanosheet remain unchanged. The composite formation with rG-O leads to a significant enhancement of the discharge capacity from 50 to 150 mAh g(-1) as cathode material for Na-ion batteries, underscoring the usefulness of restacking between metal oxide and rG-O nanosheets in exploring novel nanocomposite electrode materials. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:79 / 82
页数:4
相关论文
共 22 条
[1]  
Allen T., 2003, Powder sampling and particle size determination
[2]   Solvothermal synthesis of V2O5/graphene nanocomposites for high performance lithium ion batteries [J].
Chen, Da ;
Yi, Ran ;
Chen, Shuru ;
Xu, Terrence ;
Gordin, Mikhail L. ;
Lv, Dongping ;
Wang, Donghai .
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2014, 185 :7-12
[3]  
Condon J.B., 2006, SURFACE AREA POROSIT
[4]   Conversion of V2O5•xH2O into orthorhombic V2O5 single-crystalline nanobelts [J].
Ding, Jie ;
Peng, Hongrui ;
Li, Guicun ;
Chen, Kezheng .
MATERIALS LETTERS, 2010, 64 (14) :1562-1565
[5]   Visualization of defect densities in reduced graphene oxide [J].
Eigler, Siegfried ;
Dotzer, Christoph ;
Hirsch, Andreas .
CARBON, 2012, 50 (10) :3666-3673
[6]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339
[7]   High-Capacity Anode Materials for Sodium-Ion Batteries [J].
Kim, Youngjin ;
Ha, Kwang-Ho ;
Oh, Seung M. ;
Lee, Kyu Tae .
CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (38) :11980-11992
[8]  
LEE Y, 2011, J ELECTROCHEM SCI TE, V2, P1, DOI DOI 10.4172/2153-0602.1000106
[9]   Mixed Colloidal Suspensions of Reduced Graphene Oxide and Layered Metal Oxide Nanosheets: Useful Precursors for the Porous Nanocomposites and Hybrid Films of Graphene/Metal Oxide [J].
Lee, Yu Ri ;
Kim, In Young ;
Kim, Tae Woo ;
Lee, Jang Mee ;
Hwang, Seong-Ju .
CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (08) :2263-2271
[10]   Synthesis of nickel oxide/reduced graphene oxide composite with nanosheet-on-sheet nanostructure for lithium-ion batteries [J].
Li, Mingyan ;
Dong, Bitao ;
Gao, Guoxin ;
Ding, Shujiang .
MATERIALS LETTERS, 2015, 155 :30-33