Solvents role in the hydrogen peroxide oxidation reactions catalyzed on titanium zeolites

被引:0
作者
Hulea, V [1 ]
Oprea, S [1 ]
Ropot, R [1 ]
Dumitriu, E [1 ]
机构
[1] Univ Tehn Gh Asachi, Fac Chim Ind, Iasi, Romania
来源
REVISTA DE CHIMIE | 1998年 / 49卷 / 05期
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The influence of the solvent nature upon the oxidation reaction of diethylsulphide, di-n-butylsulfoxide and cyclopentene with hydrogen peroxide, in the presence of titanium containing zeolites was studied. It was established that the protic solvents are more efficient than the aprotic ones. The effect of solvent is less important in the case of sulfoxide oxidation. The experimental results have been explained on the basis of a reaction mechanism scheme.
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页码:336 / 344
页数:9
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