The formation of right-handed and left-handed chiral nanopores within a single domain during amino acid self-assembly on Au(111)

被引：1

作者：

Yang, Sena ^{[1
]}

Jeon, Aram ^{[1
]}

Driver, Russell W. ^{[1
]}

Kim, Yeonwoo ^{[1
]}

Jean, Eun Hee ^{[1
]}

Kim, Sehun ^{[1
]}

Lee, Hee-Seung ^{[1
]}

Lee, Hangil ^{[2
]}

机构：

[1] Korea Adv Inst Sci & Technol, Mol Level Interface Res Ctr, Dept Chem, Daejeon 305701, South Korea

[2] Sookmyung Womens Univ, Dept Chem, Seoul 140742, South Korea

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2016年 / 18卷 / 21期

基金：

新加坡国家研究基金会;

关键词：

HYDROGEN-BONDS; GROWTH; NANOSTRUCTURES; COMBINATORIAL; MONOLAYERS; SURFACES; STM;

D O I：

10.1039/c6cp01914e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report the formation of both right- and left-handed chiral nanopores within a single domain during the self-assembly of an amino acid derivative on an inert Au(111) surface using STM. DFT calculations employed to rationalize this unusual result identified that intermolecular interactions between chiral, windmill-shaped tetramers are crucial for self-assembly.

引用

页码：14172 / 14176

页数：5

共 3 条

[1] Self-Assembly of Left- and Right-Handed Molecular Screws
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[2] Self-assembly of alternating left- and right-handed infinite Cd(II) helicates into a 2D open framework structure
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[3] Separation of left- and right-handed semiconducting single-walled carbon nanotube enantiomers using achiral amino acid surfactant
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Li, Ying
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