Two cases of bipyridinium-based metal-organic frameworks: Syntheses, structures, photochromic behaviors

被引：14
|
作者：
Sun, Ya-Nan [1 ]
Li, Li [1 ]
Fu, Chen [1 ]
Wang, Hai-Yu [1 ]
Zhang, Hong [1 ]
机构：
[1] Northeast Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2018年 / 96卷
基金：
中国国家自然科学基金;
关键词：
Zinc(II) complex; Cadmium(II) complex; Crystal structure; Photochromism; Decolorization; ELECTRON-TRANSFER; COORDINATION POLYMERS; FLUORESCENT PROPERTIES; VIOLOGEN; COMPLEXES; MOF; METHYLVIOLOGEN; CRYSTAL; REDUCTION; CHLORIDE;
D O I：
10.1016/j.inoche.2018.08.006
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two novel bipyridinium-based metal-organic frameworks Zn[(pbpy)(0.5)(m-BDC)Cl]center dot 1.5H(2)O(1) and Cd [(PbPY)(0.5)(m-BDC)Cl]center dot H2O(2)center dot(PbPycl(2) = 1,1'-[1,4 phenylenebis-(methylene)This(4,4' bipyridinium) - dichloride) have been synthesized and structurally characterized by single crystal X-ray crystallography. Both of them show 2D layered window structures. When they are irradiated by 300 W Xenon lamp, both of them exhibit photochromic behaviors which are attributed to the process of intermolecular electron transfer to generate pbpycl(2) free radicals. These processes have been demonstrated by UV-Vis absorption characterization analysis, electron spin resonance (ESR). The photoproduct of compound 1 is more stable than compound 2 in air. Photochromic mechanisms and the relationships between structures and properties have been discussed adequately.
引用
收藏
页码：119 / 123
页数：5
相关论文
共 50 条
  • [21] Metal-organic frameworks: Photocatalytic application in organic syntheses
    Farrokh, Mahrokh
    IRANIAN JOURNAL OF CATALYSIS, 2024, 14 (03):
  • [22] Photochromic metal-organic frameworks for inkless and erasable printing
    Garai, Bikash
    Mallick, Arijit
    Banerjee, Rahul
    CHEMICAL SCIENCE, 2016, 7 (03) : 2195 - 2200
  • [23] Metal-Organic Frameworks as Hosts for Photochromic Guest Molecules
    Hermann, D.
    Emerich, H.
    Lepski, R.
    Schaniel, D.
    Ruschewitz, U.
    INORGANIC CHEMISTRY, 2013, 52 (05) : 2744 - 2749
  • [24] Syntheses, structures, magnetic and photoluminescence properties of metal-organic frameworks based on aromatic polycarboxylate acids
    Pan, Zhao-Rui
    Xu, Jiao
    Yao, Xiao-Qiang
    Li, Yi-Zhi
    Guo, Zi-Jian
    Zheng, He-Gen
    CRYSTENGCOMM, 2011, 13 (05): : 1617 - 1624
  • [25] Two trinuclear cluster metal-organic frameworks: syntheses, structures, highly fluorescent sensing and magnetic properties
    Rong, Jiewei
    Wang, Xiaoling
    Wen, Guilin
    Liu, Daofu
    Zhang, Wenwei
    INORGANICA CHIMICA ACTA, 2024, 565
  • [26] Two new metal-organic frameworks with different topological networks: syntheses, crystal structures and luminescent properties
    Liu, Qifeng
    INORGANIC AND NANO-METAL CHEMISTRY, 2023, 53 (10) : 1150 - 1154
  • [27] Photochromic and photomodulated luminescence properties of two metal-viologen complexes constructed by a tetracarboxylate-anchored bipyridinium-based ligand
    Li, Lin-Ke
    Li, Hai-Yang
    Li, Ting
    Quan, Li-Hong
    Xu, Jing
    Li, Fu-An
    Zang, Shuang-Quan
    CRYSTENGCOMM, 2018, 20 (41): : 6412 - 6419
  • [28] Two novel 3D metal-organic frameworks based on two tetrahedral ligands: syntheses, structures, photoluminescence and photocatalytic properties
    Guo, Jiao
    Yang, Jin
    Liu, Ying-Ying
    Ma, Jian-Fang
    CRYSTENGCOMM, 2012, 14 (20): : 6609 - 6617
  • [29] 2D metal-organic frameworks: Syntheses, structures, and electrochemical properties
    Liu, Xin
    Valentine, Haley L.
    Pan, Wei-Ping
    Cao, Yan
    Yan, Bangbo
    INORGANICA CHIMICA ACTA, 2016, 447 : 162 - 167
  • [30] Metal-Organic Frameworks in Monolithic Structures
    Kuesgens, Pia
    Zgaverdea, Alina
    Fritz, Hans-Gerhard
    Siegle, Sven
    Kaskel, Stefan
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2010, 93 (09) : 2476 - 2479
12345