Structural and electrical properties of BETS compounds with transition metal complex anions

被引：4
|
作者：
Kobayashi, H
Arai, E
Sato, A
Naito, T
Tanaka, H
Kobayashi, A
Saito, T
Cassoux, P
机构：
[1] HOKKAIDO UNIV,FAC SCI,DEPT CHEM,SAPPORO,HOKKAIDO 060,JAPAN
[2] UNIV TOKYO,SCH SCI,BUNKYO KU,TOKYO 113,JAPAN
[3] CNRS,LCC,F-31077 TOULOUSE,FRANCE
来源：
SYNTHETIC METALS | 1997年 / 85卷 / 1-3期
关键词：
organic conductors based on radical cation and/or anion salts Metal-insulator phase transitions;
D O I：
10.1016/S0379-6779(97)80365-7
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
BETS (=bis(ethylenedithio)tetraselenafulvalene) conductors with M(CN)(4) anions (M=Pd, Pt) are metallic down to 4K. Crystals of MCl4 salts (M=Co, Ni, In) are metallic down to 4 K. BETS2InCl5[(C2H5)(4)N](0.7) undergoes a gradual metal-insulator transition around 50 K. The magnetic susceptibility of BETS4Cu2Cl6 exhibits a round maximum showing an antiferromagnetic interaction between Cu2+ in Cu2Cl62- anions (J=163 K). The electrical properties and crystal structures of BETS complexes with M(dts)(2) (M=Au, Pd, Pt; dts=dithiosquarate) are briefly mentioned.
引用
收藏
页码：1595 / 1596
页数：2
相关论文
共 50 条
  • [1] Modeling of structural and spectroscopic properties of transition metal compounds
    Comba, P
    FUNDAMENTAL PRINCIPLES OF MOLECULAR MODELING, 1996, : 167 - 187
  • [2] ELECTRICAL AND STRUCTURAL-PROPERTIES OF TRANSITION-METAL DICHALCOGENIDES
    VATERLAUS, HP
    BUFFAT, P
    LEVY, F
    BERGER, H
    HELVETICA PHYSICA ACTA, 1979, 52 (5-6): : 675 - 675
  • [3] Modeling structural, spectroscopic and redox properties of transition metal compounds
    Comba, P
    IMPLICATIONS OF MOLECULAR AND MATERIALS STRUCTURE FOR NEW TECHNOLOGIES, 1999, 360 : 87 - 100
  • [4] TRANSITION METAL CHALCOGEN COMPOUNDS - THIO ANIONS AS BIDENTATE LIGANDS IN TRANSITION METAL COMPLEXES - PREPARATION AND PROPERTIES OF TETRATHIOTHUNGSTATO COMPOUNDS OF NIII,COII AND ZNII
    MULLER, A
    DIEMANN, E
    HEINSEN, HH
    CHEMISCHE BERICHTE-RECUEIL, 1971, 104 (04): : 975 - &
  • [5] Electronic properties of BETS superconductors with magnetic anions (BETS = bis(ethylenedithio)tetraselenafulvalene)
    Kobayashi, H
    Tanaka, H
    Fujiwara, H
    Tamura, I
    Gritsenko, V
    Otsuka, T
    Fujiwara, E
    Kobayashi, A
    Tokumoto, M
    Cassoux, P
    SYNTHETIC METALS, 2003, 133 : 477 - 479
  • [6] TRANSITION METAL CHALCOGEN COMPOUNDS . FORMATION AND DECOMPOSITION OF TRANSITION METAL CHALCOGEN ANIONS ON AQUEOUS SOLUTION
    MULLER, A
    GLEMSER, O
    DIEMANN, E
    HOFMEIST.H
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1969, 371 (1-2): : 74 - &
  • [7] NEW ORGANIC SUPERCONDUCTOR, LAMBDA-(BETS)(2)GACL4 AND METAL-INSULATOR-TRANSITION OF BETS CONDUCTOR WITH MAGNETIC ANIONS (BETS=BIS(ETHLENEDITHIO)TETRASELENAFULVALENE)
    KOBAYASHI, H
    TOMITA, H
    UDAGAWA, T
    NAITO, T
    KOBAYASHI, A
    SYNTHETIC METALS, 1995, 70 (1-3) : 867 - 870
  • [8] TRANSITION METAL DICHALCOGENIDES DISCUSSION AND INTERPRETATION OF OBSERVED OPTICAL, ELECTRICAL AND STRUCTURAL PROPERTIES
    WILSON, JA
    YOFFE, AD
    ADVANCES IN PHYSICS, 1969, 18 (73) : 193 - +
  • [9] A new transition metal-tellurite glass family: Electrical and structural properties
    Terny, S.
    De la Rubia, M. A.
    De Frutos, J.
    Frechero, M. A.
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 2016, 433 : 68 - 74
  • [10] EXPLORING THE MAGNETIC, ELECTRICAL AND STRUCTURAL PROPERTIES OF TRANSITION-METAL OXIDE PEROVSKITES
    Woodward, P. M.
    Karen, P.
    Goldberger, J.
    Santhosh, P. N.
    Vogt, T.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2002, 58 : C22 - C22
12345