Structural and electrical properties of BETS compounds with transition metal complex anions

被引：4

作者：

Kobayashi, H

Arai, E

Sato, A

Naito, T

Tanaka, H

Kobayashi, A

Saito, T

Cassoux, P

机构：

[1] HOKKAIDO UNIV,FAC SCI,DEPT CHEM,SAPPORO,HOKKAIDO 060,JAPAN

[2] UNIV TOKYO,SCH SCI,BUNKYO KU,TOKYO 113,JAPAN

[3] CNRS,LCC,F-31077 TOULOUSE,FRANCE

来源：

SYNTHETIC METALS | 1997年 / 85卷 / 1-3期

关键词：

organic conductors based on radical cation and/or anion salts Metal-insulator phase transitions;

D O I：

10.1016/S0379-6779(97)80365-7

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

BETS (=bis(ethylenedithio)tetraselenafulvalene) conductors with M(CN)(4) anions (M=Pd, Pt) are metallic down to 4K. Crystals of MCl4 salts (M=Co, Ni, In) are metallic down to 4 K. BETS2InCl5[(C2H5)(4)N](0.7) undergoes a gradual metal-insulator transition around 50 K. The magnetic susceptibility of BETS4Cu2Cl6 exhibits a round maximum showing an antiferromagnetic interaction between Cu2+ in Cu2Cl62- anions (J=163 K). The electrical properties and crystal structures of BETS complexes with M(dts)(2) (M=Au, Pd, Pt; dts=dithiosquarate) are briefly mentioned.

引用

页码：1595 / 1596

页数：2

共 6 条

[1] NEW ORGANIC METALS BASED ON BETS COMPOUNDS WITH MX4- ANIONS (BETS=BIS(ETHYLENEDITHIO)TETRASELENAFULVALENE - M = GA, FE, IN X = CL, BR) [J].