Synthesis of isocyanate-free polyurethane concocting multiple cyclic carbonates catalysed by a new microporous zinc phosphonate via CO2 fixation

被引:22
作者
Bhattacharjee, Sudip [1 ]
Chongdar, Sayantan [1 ]
Modak, Arindam [1 ]
Bhanja, Piyali [2 ]
Jena, Bikash Kumar [2 ]
Bhaumik, Asim [1 ]
机构
[1] Indian Assoc Cultivat Sci, Sch Mat Sci, Kolkata 700032, India
[2] CSIR, Inst Minerals & Mat Technol, Bhubaneswar 751013, India
关键词
DIOXIDE; CAPTURE; CYCLOADDITION; ADSORPTION; EPOXIDES;
D O I
10.1039/d2gc02959f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Chemical fixation of carbon dioxide (CO2) on reactive organics is very challenging from the perspective of sustainable synthesis of fine chemicals and mitigation of this abundant greenhouse gas. Herein, we report the synthesis of a novel microporous zinc phosphonate (ZnGLy) using N,N-bis(phosphonomethyl)glycine as a bridging phosphonate precursor under hydrothermal reaction conditions. The high surface area with regular microporous channels, along with the presence of both Lewis acidic and basic sites in ZnGLy, has motivated us to explore its catalytic potential for the chemical fixation of CO2 over a series of reactive organic molecules. ZnGLy exhibited excellent catalytic performance for the synthesis of mono- to tetra-cyclic carbonates, including biologically active epoxides, at moderate CO2 pressure. Utilizing CO2 as a C1 source, this material also displayed excellent catalytic activity towards the synthesis of value added hydroxy carbamates. The bis-cyclic carbonate synthesized herein was further used for the synthesis of isocyanate-free poly(hydroxy)urethane. Furthermore, ZnGLy exhibited outstanding recyclability for several catalytic cycles with the retention of its framework, suggesting its huge potential as a heterogeneous catalyst for large scale CO2 fixation reactions.
引用
收藏
页码:8853 / 8862
页数:10
相关论文
共 47 条
[21]   Crystalline zinc diphosphonate metal-organic framework with three-dimensional microporosity [J].
Liang, Junmei ;
Shimizu, George K. H. .
INORGANIC CHEMISTRY, 2007, 46 (25) :10449-10451
[22]   Metal-decorated porous organic frameworks with cross-linked pyridyl and triazinyl as efficient platforms for CO2 activation and conversion under mild conditions [J].
Liu, Fangwang ;
Duan, Xinran ;
Dai, Xun ;
Du, Shanshan ;
Ma, Jingjing ;
Liu, Fusheng ;
Liu, Mengshuai .
CHEMICAL ENGINEERING JOURNAL, 2022, 445
[23]   Construction of zwitterionic porous organic frameworks with multiple active sites for highly efficient CO2 adsorption and synergistic conversion [J].
Liu, Fangwang ;
Du, Shanshan ;
Zhang, Wenwen ;
Ma, Jingjing ;
Wang, Shasha ;
Liu, Mengshuai ;
Liu, Fusheng .
CHEMICAL ENGINEERING JOURNAL, 2022, 435
[24]   Periodic mesoporous titanium phosphonate hybrid materials [J].
Ma, Tian-Yi ;
Lin, Xiu-Zhen ;
Yuan, Zhong-Yong .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (35) :7406-7415
[25]   Recent progress in catalytic conversions of carbon dioxide [J].
Maeda, Chihiro ;
Miyazaki, Yuki ;
Ema, Tadashi .
CATALYSIS SCIENCE & TECHNOLOGY, 2014, 4 (06) :1482-1497
[26]   Synthesis, characterizations and Pb(II) sorption properties of cobalt phosphonate materials [J].
Maranescu, Bianca ;
Lupa, Lavinia ;
Visa, Aurelia .
PURE AND APPLIED CHEMISTRY, 2016, 88 (10-11) :979-992
[27]   The teraton challenge. A review of fixation and transformation of carbon dioxide [J].
Mikkelsen, Mette ;
Jorgensen, Mikkel ;
Krebs, Frederik C. .
ENERGY & ENVIRONMENTAL SCIENCE, 2010, 3 (01) :43-81
[28]   Silver nanoparticles embedded over porous metal organic frameworks for carbon dioxide fixation via carboxylation of terminal alkynes at ambient pressure [J].
Molla, Rostam Ali ;
Ghosh, Kajari ;
Banerjee, Biplab ;
Iqubal, Md. Asif ;
Kundu, Sudipta K. ;
Islam, Sk. Manirul ;
Bhaumik, Asim .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2016, 477 :220-229
[29]   Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of β-diketones [J].
Montoya, Carmen A. ;
Gomez, Clara F. ;
Paninho, Ana B. ;
Nunes, Ana V. M. ;
Mahmudov, Kamran T. ;
Najdanovic-Visak, Vesna ;
Martins, Luisa M. D. R. S. ;
Guedes da Silva, M. Fatima C. ;
Pombeiro, Armando J. L. ;
da Ponte, Manuel Nunes .
JOURNAL OF CATALYSIS, 2016, 335 :135-140
[30]   Poly(hydroxyurethane): catalytic applicability for the cyclic carbonate synthesis from epoxides and CO2 [J].
Motokucho, Suguru ;
Morikawa, Hiroshi .
CHEMICAL COMMUNICATIONS, 2020, 56 (73) :10678-10681