Optical properties of vitrified rare-earth soaps

被引:18
作者
Binnemans, K [1 ]
Jongen, L [1 ]
Görller-Walrand, C [1 ]
机构
[1] Katholieke Univ Leuven, Dept Chem, B-3001 Heverlee, Belgium
关键词
D O I
10.1039/b105509g
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Transparent glass samples were obtained by fast cooling of molten lanthanide(III) octadecanoates Ln(C17H35COO)(3) (lanthanide = neodymium, samarium, europium, gadolinium, dysprosium, holmium, erbium). The tendency of the material to crystallise is reduced by the presence of long alkyl chains. Absorption and luminescence spectra were recorded. The intensities of the f-f transitions were parametrised within the framework of the Judd-Ofelt theory.
引用
收藏
页码:4796 / 4799
页数:4
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